The first and Third graph
<h3><u>Full Question:</u></h3>
The following compound has been found effective in treating pain and inflammation (J. Med. Chem. 2007, 4222). Which sequence correctly ranks each carbonyl group in order of increasing reactivity toward nucleophilic addition?
A) 1 < 2 < 3
B) 2 < 3 < 1
C) 3 < 1 < 2
D) 1 < 3 < 2
<h3><u>Answer: </u></h3>
The rate of nucleophilic attack of carbonyl compounds is 2<3 <1.
Option B
<h3><u>Explanation. </u></h3>
Nucleophilic attack is explained as the attack of an electron rich radical to a carbonyl compound like aldehyde or a ketone. A nucleophile has a high electron density, so it searches for a electropositive atom where it can donate a portion of its electron density and become stable.
A carbonyl compound is a 
hybridized carbon atom with a double bonded oxygen atom in it. The oxygen atom pulls a huge portion of electron density from carbon being very electropositive.
In a ketone, there are two factors that make it less likely to undergo a nucleophilic attack than aldehyde. Firstly, the steric hindrance of two carbon groups being attached with the carbonyl carbon makes it harder for the nucleophile to approach. Secondly, the electron push by the carbon groups attached makes the carbonyl carbon a bit less electropositive than the aldehyde one. So aldehydes are more reactive towards a nucleophilic addition reaction.
<u>Answer:</u>
Pyrite leaves behind a green-black streak when it is rubbed against an unglazed porcelain plate as a part of the streak test process.
<u>Explanation:</u>
Different minerals produce different coloured streaks when rubbed against a white ceramic or porcelain streak plate. This streak test is done to identify the mineral and distinguish the same from other minerals that look similar in colour and texture.
It must be ensured that the test is done on clean and fresh specimens of the mineral and that there must be no contaminants. Pyrite specimens are usually brass-yellow colour but it leaves a green-black streak when the streak test is done.
When a substance absorbs thermal energy, it partitions some as potential and some as kinetic energy. Specific heat is an expression related to the quantity of heat a substance stores as potential energy; the remainder is absorbed as kinetic which causes the temperature to increase - recall that temperature is a measure of average kinetic energy.
When specific heat is low, most of the energy is partitioned as kinetic energy and the substance will experience the greatest temperature change.
So rather than calculating the change in temperature, we can simply inspect the specific heats. The one with the lowest will experience the greatest temperature change. We could also compare the specific heats: Al = .897/.385 ==> 2.3, Fe = .452/.385 = 1.2, Cu = .385/.385 = 1. We can expect Copper's temperature change to be 2.3 times larger than Aluminum's and 1.2 times larger than Iron's.
