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Below is the mechanism showing the hydrolysis of Iminium Ion into aldehye. The arrows are shown in RED.
Answer:
False
Explanation:
Laboratory synthesis of aspirin is done by the acetylation of salicylic acid with the help of acetic anhydride .
As , the acid anhydride is very sensitive to moisture , as it can hydrolyze into two molecules of acids,
Hence , the reaction involving acid anhydride are conducted in anhydrous solvents .
Hence ,
if water is present in the glassware then , some of the acetic anhydride is wasted , Which in turns reduces the yield than that expected .
Answer:
(i) ΔU = 116 J
(ii) ΔU = 289 J
(iii) ΔU = 1 KJ
(iv) ΔU = 0 J
(v) ΔU = 3.25 KJ
Explanation:
first law:
(i) W = 153 J; Q = - 37 J ( Q ( - ), losing friction )
⇒ ΔU = 153 - 37 = 116 J
(ii) W = 289 J; Q = 0 ( insulated)
⇒ ΔU = W = 289 J
(iii) Q = 1 KJ , W = 0 ( isovolumetric process)
⇒ ΔU = Q = 1 KJ
(iv) isothermal ( constant temperature )
∴ ΔT = 0° ( isothermal )
⇒ ΔU = 0 J
(v) isobaric ( constant pressure )
⇒ ΔU = Q + W
∴ Q = 15.6 KJ
∴ W = - ∫ P dV = - P ΔV; W (-) the system performs a job and the volume increases
.
∴ P = 950 KPa * ( 1000 Pa / KPa ) = 950000 Pa = 950000 J/m³
∴ ΔV = 18 - 5 = 13 L * ( m³ / 1000 L ) = 0.013 m³
⇒ W = - ( 950000 J/m³) * ( 0.013 m³ ) = - 12350 J ( - 12.35 KJ )
⇒ ΔU = 15.6 KJ + ( - 12.35 KJ )
⇒ ΔU = 3.25 KJ
