Octet means presence of a total of 8 electrons in its valence shell while in case of duplet only 2 electrons are present in valence shell.
The molar extinction coefficient is 15,200
.
The formula to be used to calculate molar extinction coefficient is -
A = ξcl, where A represents absorption, ξ refers molar extinction coefficient, c refers to concentration and l represents length.
The given values are in required units, hence, there is no need to convert them. Directly keeping the values in formula to find the value of molar extinction coefficient.
Rewriting the formula as per molar extinction coefficient -
ξ = 
ξ = 
Performing multiplication in denominator to find the value of molar extinction coefficient
ξ =
Performing division to find the value of molar extinction coefficient
ξ = 15,200 
Hence, the molar extinction coefficient is 15,200
.
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Answer : The value of
for the reaction is -959.1 kJ
Explanation :
The given balanced chemical reaction is,

First we have to calculate the enthalpy of reaction
.

![\Delta H^o=[n_{H_2O}\times \Delta H_f^0_{(H_2O)}+n_{SO_2}\times \Delta H_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta H_f^0_{(H_2S)}+n_{O_2}\times \Delta H_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20H_f%5E0_%7B%28O_2%29%7D%5D)
where,
= enthalpy of reaction = ?
n = number of moles
= standard enthalpy of formation
Now put all the given values in this expression, we get:
![\Delta H^o=[2mole\times (-242kJ/mol)+2mole\times (-296.8kJ/mol)}]-[2mole\times (-21kJ/mol)+3mole\times (0kJ/mol)]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo%3D%5B2mole%5Ctimes%20%28-242kJ%2Fmol%29%2B2mole%5Ctimes%20%28-296.8kJ%2Fmol%29%7D%5D-%5B2mole%5Ctimes%20%28-21kJ%2Fmol%29%2B3mole%5Ctimes%20%280kJ%2Fmol%29%5D)

conversion used : (1 kJ = 1000 J)
Now we have to calculate the entropy of reaction
.

![\Delta S^o=[n_{H_2O}\times \Delta S_f^0_{(H_2O)}+n_{SO_2}\times \Delta S_f^0_{(SO_2)}]-[n_{H_2S}\times \Delta S_f^0_{(H_2S)}+n_{O_2}\times \Delta S_f^0_{(O_2)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5Bn_%7BH_2O%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2O%29%7D%2Bn_%7BSO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28SO_2%29%7D%5D-%5Bn_%7BH_2S%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28H_2S%29%7D%2Bn_%7BO_2%7D%5Ctimes%20%5CDelta%20S_f%5E0_%7B%28O_2%29%7D%5D)
where,
= entropy of reaction = ?
n = number of moles
= standard entropy of formation
Now put all the given values in this expression, we get:
![\Delta S^o=[2mole\times (189J/K.mol)+2mole\times (248J/K.mol)}]-[2mole\times (206J/K.mol)+3mole\times (205J/K.mol)]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo%3D%5B2mole%5Ctimes%20%28189J%2FK.mol%29%2B2mole%5Ctimes%20%28248J%2FK.mol%29%7D%5D-%5B2mole%5Ctimes%20%28206J%2FK.mol%29%2B3mole%5Ctimes%20%28205J%2FK.mol%29%5D)

Now we have to calculate the Gibbs free energy of reaction
.
As we know that,

At room temperature, the temperature is 500 K.


Therefore, the value of
for the reaction is -959.1 kJ
He can conclude that his experiment has very low precision.
<h3>What is Precision ?</h3>
Precision is defined as the degree of refinement with which an operation is performed or a measurement .
Precision is how close the exact answers are together.
As, the answers are increasing in time.
None of the answers are similar to one another.
Hence, He can conclude that his experiment has very low precision.
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