The quantity of NaOH required to reach the third equivalence point is 20mL.
Using the titration formula,
CaVa/CbVb = Na/Nb
Where,
Ca = concentration of citric acid (0.200 M)
Cb = concentration of NaOH (0.750 M)
Va = Volume of citric acid (25.0 mL)
Vb = volume of NaOH (x mL)
Na = number of reacting mole of citric acid (3)
Nb = number of reacting mole of NaOH (1)
Therefore Vb ( x mL) =CaVaNb/CbNa
= 0.2× 25×3/0.75 ×1
= 15/0.75
Vb ( x mL) = 20 mL
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