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Convert the composition of the following alloy from atom percent to weight percent (a) 44.9 at% of silver, (b) 46.3 at% of gold,

vesna_86 [32]

Answer:

Mass percentage of gold : 33.35%

Mass percentage of silver: 62.80%

Mass percentage of copper : 3.85%

Explanation:

$N=n\times N_A$

Where : N = Number of atoms

n = moles

$N_A=6.022\times 10^{23}$ = Avogadro number

Let the total atoms present in the alloy be 100.

Atom percentage of silver = 44.9%

Atoms of of silver = 44.9% of 100 atoms = 44.9

Atomic weight of silver = 107.87 g/mol

Mass of 44.9 silver atoms = 107.87 g/mol × 44.9 = 4,843.363 g/mol

Atom percentage of gold= 46.3%

Atoms of of gold = 46.3% of 100 atoms = 46.3

Atomic weight of gold = 196.97 g/mol

Mass of 44.9 gold atoms = 196.97 g/mol × 46.3 = 9,119.711 g/mol

Atom percentage of copper = 8.8 %

Atoms of of copper = 8.8% of 100 atoms = 8.8

Atomic weight of copper = 63.55 g/mol

Mass of 44.9 copper atoms = 63.55 g/mol × 8.8 = 559.24 g/mol

Total mass of an alloy :4,843.363 g/mol + 9,119.711 g/mol + 559.24 g/mol

Mass percentage of gold :

$\frac{4,843.363 g/mol}{4,843.363 g/mol + 9,119.711 g/mol + 559.24 g/mol}\times 100=33.35 \%$

Mass percentage of silver:

$\frac{9,119.711 g/mol}{4,843.363 g/mol + 9,119.711 g/mol + 559.24 g/mol}\times 100=62.80\%$

Mass percentage of copper :

$\frac{559.24 g/mol}{4,843.363 g/mol + 9,119.711 g/mol + 559.24 g/mol}\times 100=3.85\%$

7 0

3 years ago

Be sure to answer all parts. Calculate the pH during the titration of 30.00 mL of 0.1000 M KOH with 0.1000 M HBr solution after

Fantom [35]

Answer:

(a) pH = 12.73

(b) pH = 10.52

(c) pH = 1.93

Explanation:

The net balanced reaction equation is:

KOH + HBr ⇒ H₂O + KBr

The amount of KOH present is:

n = CV = (0.1000 molL⁻¹)(30.00 mL) = 3.000 mmol

(a) The amount of HBr added in 9.00 mL of 0.1000 M HBr is:

(0.1000 molL⁻¹)(9.00 mL) = 0.900 mmol

This amount of HBr will neutralize an equivalent amount of KOH (0.900 mmol), leaving the following amount of KOH:

(3.000 mmol) - (0.900 mmol) = 2.100 mmol KOH

After the addition of HBr, the volume of the KOH solution is 39.00 mL. The concentration of KOH is calculated as follows:

C = n/V = (2.100 mmol) / (39.00 mL) = 0.0538461 M KOH

The pOH and pH of the solution can then be calculated:

pOH = -log[OH⁻] = -log(0.0538461) = 1.2688

pH = 14 - pOH = 14 - 1.2688 = 12.73

(b) The amount of HBr added in 29.80 mL of 0.1000 M HBr is:

(0.1000 molL⁻¹)(29.80 mL) = 2.980 mmol

This amount of HBr will neutralize an equivalent amount of KOH, leaving the following amount of KOH:

(3.000 mmol) - (2.980 mmol) = 0.0200 mmol KOH

After the addition of HBr, the volume of the KOH solution is 59.80 mL. The concentration of KOH is calculated as follows:

C = n/V = (0.0200 mmol) / (59.80 mL) = 0.0003344 M KOH

The pOH and pH of the solution can then be calculated:

pOH = -log[OH⁻] = -log(0.0003344) = 3.476

pH = 14 - pOH = 14 - 3.476 = 10.52

(c) The amount of HBr added in 38.00 mL of 0.1000 M HBr is:

(0.1000 molL⁻¹)(38.00 mL) = 3.800 mmol

This amount of HBr will neutralize all of the KOH present. The amount of HBr in excess is:

(3.800 mmol) - (3.000 mmol) = 0.800 mmol HBr

After the addition of HBr, the volume of the analyte solution is 68.00 mL. The concentration of HBr is calculated as follows:

C = n/V = (0.800 mmol) / (68.00 mL) = 0.01176 M HBr

The pH of the solution can then be calculated:

pH = -log[H⁺] = -log(0.01176) = 1.93

4 0

3 years ago

PLEASE HELP ME ASAPPP!?

Brrunno [24]

lets guess and say #4???

7 0

3 years ago

Will alka-seltzer fizz when added to apple juice?

Naddik [55]

Yes but only if you're talking about treated apple juice with a naturally small amount of water mixed in.

4 0

3 years ago

Mg(ClO2)2 and Al(ClO2)3 contain the same number of atoms

Vladimir [108]

<span>Mg(ClO2)2 has an atom of magnesium, 2 moles of chlorine and 4 moles of oxygen. </span><span>Al(ClO2)3, on the other hand, is composed of one mole of aluminum, one mole of chlorine and six moles of oxygen. The number of molecules of both is equal to 6.022 x10^23 molecules per mole of the compound.</span>

7 0

3 years ago