Answer:
See explanation and images attached
Explanation:
a) In the mechanism for the acid catalysed esterification of propanoic acid using ethanol, we can see that the first step is the protonation of the acid followed by nucleophillic attack of the alcohol. Loss of water and consequent deprotonation regenerates the acid catalyst. We can see the fate of the 18O labelled ethanol in the mechanism shown.
b) In the second mechanism, an unnamed ester is hydrolysed using an acid catalyst. The attack of the acid and subsequent nucleophillic attack of water labelled with 18O leads to the incorporation of this 18O into the product acid as shown in the mechanism attached to this answer.
Answer:
A. percentage mass of iron = 5.17%
percentage mass of sand = 8.62%
percentage mass of water = 86.205%
B. (Iron + sand + water) -------> ( iron + sand) ------> sand
C. The step of separation of iron and sand
Explanation:
A. Percentage mass of the mixtures:
Total mass of mixture = (15.0 + 25.0 + 250.0) g =290.0 g
percentage mass of iron = 15/290 * 100% = 5.17%
percentage mass of sand = 25/290 * 100% = 8.62%
percentage mass of water = 250/290 * 100% = 86.205%
B. Flow chart of separation procedure
(Iron + sand + water) -------> separation by filtration using filter paper and funnel to remove water --------> ( iron + sand) -----------> separation using magnet to remove iron ------> sand
C. The step of separation of iron and sand by magnetization of iron will have the highest amount of error because during the process, some iron particles may not readily be attracted to the magnet as they may have become interlaced in-between sand grains. Also, some sand particle may also be attracted to the magnet as they are are borne on iron particles.
Answer:
In Haloarenes the C atom to which the X group is attached is SP2 hybridized thus it is become difficult to replace it by the Nucleophile. Since arenes and Vinyl halides are electron rich molecules due to presenceof n bonds, they repel Nucleophile attacking them.