They discovered that *elements* show increase in atomic numbers across the period.
<span>5.5×10−2M in calcium chloride and 8.0×10−2M in magnesium nitrate.
What mass of sodium phosphate must be added to 1.5L of this solution to completely eliminate the hard water ion
1) Content of Ca (2+) ions
Calcium chloride = CaCl2
Ionization equation: CaCl2 ---> Ca (2+) + 2 Cl (-)
=> Molar ratios: 1 mol of CaCl2 : 1 mol Ca(2+) : 2 mol Cl(-)
Calculate the number of moles of CaCl2 in 1.5 liters of 5.5 * 10^-2 M solution
M = n / V => n = M*V = 5.5 * 10^ -2 M * 1.5 l = 0.0825 mol CaCl2
=> 0.0825 mol Ca(2+)
2) Number of phosphate ions needed to react with 0.0825 mol Ca(2+)
formula of phospahte ion: PO4 (3-)
molar ratio: 2PO4(3-) + 3Ca(2+) = Ca3 (PO4)2
Proportion: 2 mol PO4(3-) / 3 mol Ca(2+) = x / 0.0825 mol Ca(2+)
=> x = 0.0825 coml Ca(2+) * 2 mol PO4(3-) / 3 mol Ca(2+) = 0.055 mol PO4(3-)
3) Content of Mg(2+) ions
Ionization equation: Mg (NO3)2 ----> Mg(2+) + 2 NO3 (-)
Molar ratios: 1 mol Mg(NO3)2 : 1 mol Mg(2+) + 2 mol NO3(-)
number of moles of Mg(NO3)2 in 1.5 liter of 8.0 * 10^-2 M solution
n = M * V = 8.0 * 10^ -2 M * 1.5 liter = 0.12 moles Mg(NO3)2
ions of Mg(2+) = 0.12 mol Mg(NO3)2 * 1 mol Mg(2+) / mol Mg(NO3)2 = 0.12 mol Mg(2+)
4) Number of phosphate ions needed to react with 0.12 mol Mg(2+)
2PO4(3-) + 3Mg(2+) = Mg3(PO4)2
=> 2 mol PO4(3-) / 3 mol Mg(2+) = x / 0.12 mol Mg(2+)
=> x = 0.12 * 2/3 mol PO4(3-) = 0.16 mol PO4(3-)
5) Total number of moles of PO4(3-)
0.055 mol + 0.16 mol = 0.215 mol
6) Sodium phosphate
Sodium phosphate = Na3(PO4)
Na3PO4 ---> 3Na(+) + PO4(3-)
=> 1 mol Na3PO4 : 1 mol PO4(3-)
=> 0.215 mol PO4(3-) : 0.215 mol Na3PO4
mass in grams = number of moles * molar mass
molar mass of Na3 PO4 = 3*23 g/mol + 31 g/mol + 4*16 g/mol = 164 g/mol
=> mass in grams = 0.215 mol * 164 g/mol = 35.26 g
Answer: 35.26 g of sodium phosphate
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Above it says the molecular weights are
NH3- 17g/mol and SF6-146 g/mol
Well 1 mole of SF6 is 146.048 grams (i added hte atomic masses of each element). So then the number of moles in 0.85 grams would be 0.00582000438 moles.
<span><span><span>= 1mole / </span><span>146.048g *</span></span> 0.85g</span>
so we would need 0.00582000438 moles of NH3 to have the same number of molecules.
One mole of NH3 is 17.030519999989988 grams (i added each atoms mass). so 0.00582000438 moles of NH3 would be:
<span><span><span>= 17.030519999989988 g / </span><span>mole * </span></span>0.00582000438moles</span>
that equals 0.09911770099 grams.
so 0.09911770099 grams is the answer if you round that you get about 0.1 grams
Answer:
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