Answer:
See explanation.
Explanation:
For the ideal gas law (PV = nRT), we can notice that when the temperatures increases, the pressure or the volume must increase.
For the container with constant volume, the pressure will increase. Because density is mass/volume, in this container the density will not change.
For the other container, the pressure must be the same as the external, so it will not change, then the volume must increase. When the volume increases, the density decreases (density = mass/volume), so the pressure doesn't change and the density decreases.
Answer:decomposition reaction
Explanation:it is a decomposition reaction
The pH a 0.25 m solution of C₆H₅NH₂ is equal to 3.13.
<h3>How do we calculate pH of weak base?</h3>
pH of the weak base will be calculate by using the Henderson Hasselbalch equation as:
pH = pKb + log([HB⁺]/[B])
pKb = -log(1.8×10⁻⁶) = 5.7
Chemical reaction for C₆H₅NH₂ is:
C₆H₅NH₂ + H₂O → C₆H₅NH₃⁺ + OH⁻
Initial: 0.25 0 0
Change: -x x x
Equilibrium: 0.25-x x x
Base dissociation constant will be calculated as:
Kb = [C₆H₅NH₃⁺][OH⁻] / [C₆H₅NH₂]
Kb = x² / 0.25 - x
x is very small as compared to 0.25, so we neglect x from that term and by putting value of Kb, then the equation becomes:
1.8×10⁻⁶ = x² / 0.25
x² = (1.8×10⁻⁶)(0.25)
x = 0.67×10⁻³ M = [C₆H₅NH₃⁺]
On putting all these values on the above equation of pH, we get
pH = 5.7 + log(0.67×10⁻³/0.25)
pH = 3.13
Hence pH of the solution is 3.13.
To know more about Henderson Hasselbalch equation, visit the below link:
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The energy increases because the molecules in water move faster
Answer:
See explanation.
Explanation:
Since potassium tert-butoxide is a strong bulky base, we expect that an elimination reaction predominates.
This reaction is expected to occur by E2 mechanism. The cis isomer of 1-bromo-4-tert-butylcyclohexane is known to react faster by E2 mechanism because it fulfills the anticoplanar arrangement required for for E2 mechanism, where the leaving group and adjacent proton must be anti to each other and in the same plane. The trans isomer can not fulfill this requirement.