You titrate 25.0 mL of HCl solution of an unknown concentration with a 0.190 M NaOH solution. Complete neutralization of the HCl
1 answer:
A titration is defined as 'the process of determining the quantity of a substance A by adding measured increments of substance B, the titrant, with which it reacts until exact chemical equivalence is achieved (the equivalence point)'.
The Molarity of the HCl Solution requires the addition of 24.6 mL of titrant is 0.0836 M (to 3 significant figures)
<h3>What is Titrant?</h3>A reagent solution of precisely known concentration that is added in titration
Given reaction HCl + NaOH ===> NaCl + neutralization reaction
Note that the mole ratio is 1:1 meaning that 1 mole HCl reacts with 1 mole NaOH to produce 1 mole NaCl and 1 mole
Find moles of NaOH used:
18.45 ml x 1 L/1000 ml x 0.085 mol/L = 0.002091 moles NaOH used
This meant that there must be 0.002091 moles of HCl present in the 25.0 mls.
We want to find the molarity (M) which is moles HCl/liter of solution. We know the moles, and we also know the liters of solution (25.0 mls x 1 L / 1000 mls = 0.025 liters)
M = 0.002091 moles HCl / 0.025 liters = 0.08364 M = 0.0836 M (to 3 significant figures)
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The question is missing the molecules in which the integration ratio of 2:3 will be observed. The complete question is given in the attachment.
Answer:
Molecule (a), (c), and (f) will show two peaks with the integration ratio of 2:3 in their 1H NMR spectrum
Explanation:
In the 1H NMR spectrum, the peak area is dependent on the number of hydrogen in a specific chemical environment. Hence, the ratio of the integration of these signals provides us with the relative number of hydrogen in two peaks. This rationale is used for the assignment of molecules that will give 2:3 integration ratio in the given problem.
- Molecule (a) have two CH₂ and three CH₃ groups. Hence, it will give two peaks and their integration ratio becomes 2:3 (Answer)
- Molecule (b) contains three chemical environments for its hydrogen atoms
- Molecule (c) have a single CH₂ and CH₃ group giving integration ratio of 2:3 (Answer)
- Molecule (d) will give two peaks but their ratio will be 1:3 because of two hydrogens of CH₂ and six hydrogens from two CH₃ groups
- Molecule (e) have three CH and three CH₃ groups, so their ratio will become 1:3
- Molecule (f) contains four CH and two CH₃ groups, giving two peaks. So, the integration ratio of their peaks is 2:3 (Answer)
- Molecules
- (g)
- and
- (h)
- both have two CH and two CH₃ groups giving two peaks with the integration ratio of 1:3
