What is the chemical formula for iron(II) hydroxide?
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Answer:
The molar concentration of Cu²⁺ in the initial solution is 6.964x10⁻⁴ M.
Explanation:
The first step to solving this problem is calculating the number of moles of Cu(NO₃)₂ added to the solution:
n = 1.375x10⁻⁵ mol
The second step is relating the number of moles to the signal. We know the the n calculated before is equivalent to a signal increase of 19.9 units (45.1-25.2):
1.375x10⁻⁵ mol _________ 19.9 units
x _________ 25.2 units
x = 1.741x10⁻⁵mol
Finally, we can calculate the Cu²⁺ concentration :
C = 1.741x10⁻⁵mol / 0.025 L
C = 6.964x10⁻⁴ M
The mass of ammonium chloride that must be added is : ( A ) 4.7 g
<u>Given data :</u>
Volume of water ( V ) = 250 mL = 0.25 L
pH of solution = 4.85
Kb = 1.8 * 10⁻⁵
Kw = 10⁻¹⁴
Given that the dissolution of NH₄Cl gives NH₄⁺⁺ and Cl⁻ ions the equation is written as :
NH₄CI + H₂O ⇄ NH₃ + H₃O⁺
where conc of H₃O⁺
[ H₃O⁺ ] = and Ka = Kw / Kb
∴ Ka = 5.56 * 10⁻¹⁰
Next step : Determine the concentration of H₃O⁺ in the solution
pH = - log [ H₃O⁺ ] = 4.85
∴ [ H₃O⁺ ] in the solution = 1.14125 * 10⁻⁵
Next step : Determine the concentration of NH₄CI in the solution
C = [ H₃O⁺ ]² / Ka
= ( 1.14125 * 10⁻⁵ )² / 5.56 * 10⁻¹⁰
= 0.359 mol / L
Determine the number of moles of NH₄CI in the solution
n = C . V
= 0.359 mol / L * 0.25 L = 0.08979 mole
Final step : determine the mass of ammonium chloride that must be added to 250 mL
mass = n * molar mass
= 0.08979 * 53.5 g/mol
= 4.80 g ≈ 4.7 grams
Therefore we can conclude that the mass of ammonium chloride that must be added is 4.7 g
Learn more about ammonium chloride : brainly.com/question/13050932