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1 year ago

Calculate the molarity of a Ba(OH)2 solution if 1950 mL is completely titrated by 26.1 mL of 0.505 M HNO3

Chemistry

1 answer:

kifflom [539]1 year ago

4 0

Answer: 0.01 M

Explanation:

$M_{A}V_{A}=M_{B}V_{B}\\(26.1)(0.505)=(1950)M_{B}\\M_{B}=\frac{(26.1)(0.505)}{1950} \approx \boxed{0.01 \text{ M}}$

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In the Haber process for ammonia synthesis, K " 0.036 for N 2 (g) ! 3 H 2 (g) ∆ 2 NH 3 (g) at 500. K. If a 2.0-L reactor is char

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Answer : The partial pressure of $N_2,H_2\text{ and }NH_3$ at equilibrium are, 1.133, 2.009, 0.574 bar respectively. The total pressure at equilibrium is, 3.716 bar

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Initial pressure of $N_2$ = 1.42 bar

Initial pressure of $H_2$ = 2.87 bar

$K_p$ = 0.036

The given equilibrium reaction is,

$N_2(g)+H_2(g)\rightleftharpoons 2NH_3(g)$

Initially 1.42 2.87 0

At equilibrium (1.42-x) (2.87-3x) 2x

The expression of $K_p$ will be,

$K_p=\frac{(p_{NH_3})^2}{(p_{N_2})(p_{H_2})^3}$

Now put all the values of partial pressure, we get

$0.036=\frac{(2x)^2}{(1.42-x)\times (2.87-3x)^3}$

By solving the term x, we get

$x=0.287\text{ and }3.889$

From the values of 'x' we conclude that, x = 3.889 can not more than initial partial pressures. So, the value of 'x' which is equal to 3.889 is not consider.

Thus, the partial pressure of $NH_3$ at equilibrium = 2x = 2 × 0.287 = 0.574 bar

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The partial pressure of $H_2$ at equilibrium = (2.87-3x) = [2.87-3(0.287)] = 2.009 bar

The total pressure at equilibrium = Partial pressure of $N_2$ + Partial pressure of $H_2$ + Partial pressure of $NH_3$

The total pressure at equilibrium = 1.133 + 2.009 + 0.574 = 3.716 bar

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