Choice B I think, because if the temperature decreases the particles move slower due to less kinetic energy, and thus won't collide as frequently.
Equilibrium is reached when the net reaction is zero. The reaction is consistent, when reactants and products are neither excessively consumed, nor produced.
The rate of the forward reaction is equal to the rate of the reverse reaction.
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The balanced reaction equation for the reaction between CH₃OH and O₂ is
2CH₃OH(l) + 3O₂(g) → 2CO₂(g) + 4H₂O(l)
Initial moles 12 24
Reacted moles 12 18
Final moles - 6 12 24
The stoichiometric ratio between CH₃OH and O₂ is 2 : 3
Hence,
reacted moles of O₂ = reacted moles of CH₃OH x (3/2)
= 12 mol x 3 / 2
= 18 mol
All of CH₃OH moles react with O₂.
Hence, the limiting agent is CH₃OH.
Excess reagent is O₂.
Amount of moles of excess reagent left = 24 - 18 mol = 6 mol