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rosijanka [135]
3 years ago
11

15.5 g of an unknown metal at 165.0°C is dropped into 150.0mL of H2O at 23.0°C in a coffee cup calorimeter. The metal and H2O re

ached thermal equilibrium at 30.0°C. Calculate the specific heat capacity of the unknown metal. Specific heat of water is 4.184 J/g°C.
Chemistry
1 answer:
tino4ka555 [31]3 years ago
4 0

Answer:

Specific heat capacity of metal is 2.09 j/g.°C.

Explanation:

Specific heat capacity:

It is the amount of heat required to raise the temperature of one gram of substance by one degree.

Formula:

Q = m.c. ΔT

Q = amount of heat absorbed or released

m = mass of given substance

c = specific heat capacity of substance

ΔT = change in temperature

Given data:

Mass of metal = 15.5 g

Initial temperature = 165.0°C

Initial temperature of water = 23.0°C

Final temperature = 30.0°C

Specific heat capacity of metal = ?

Specific heat capacity of water = 4.184 J/g°C

Volume of water = 150.0 mL or 150.0 g

Solution:

Formula:

- Qm  =  +Qw

Now we will put the values in formula.

-15.5 g × c × [ 30.0°C - 165.0°C] = 150 g × 4.184 J/g°C × [ 30.0°C - 23.0°C]

15.5 g × c × 135°C = 4393.2 j

2092.5 g.°C  × c = 4393.2 j

c = 4393.2 j/2092.5 g.°C  

c = 2.09 j/g.°C  

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A dark brown binary compound contains oxygen and a metal. It is 13.38% oxygen by mass. Heating it moderately drives off some of
Leto [7]

Answer:

a) Mass of O in compound A = 32.72 g

Mass of O in compound B =  21.26 g

Mass of O in compound C = 15.94 g

b) Compound A = MO2

Compound B = M3O4

Compound C = MO

c) M = Pb

Explanation:

Step 1: Data given

A binairy compound contains oxygen (O) and metal (M)

⇒ 13.38 % O

⇒ 100 - 13.38 = 86.62 % M

After heating we get another binairy compound

⇒ 9.334 % O

⇒ 100 - 9.334 = 90.666 % M

After heating we get another binairy compound

⇒ 7.168 % O

⇒ 100 - 7.168 = 92.832 % M

The first compound has an empirical formula of MO2

⇒ 1 mol M for 2 moles O

Step 2: Calculate amount of metal and oxygen in each

compound A:   M  = m1 *0.8662    O = m1 *0.1338

compound B:   M  = m2 *0.90666    O = m2 *0.09334

compound C:   M  = m3 *0.92832    O = m3 *0.07168

Step 3: Calculate mass of oxygen with 1.000 grams of M

Compound A: 1.000g * 0.1338 m1gO  / 0.8662m1gMetal = 0.1545

Compound B: 1.000g * 0.09334 m2gO  / 0.90666m2gMetal = 0.1029

Compound C: 1.000g * 0.07168 m3gO  / 0.92832m3gMetal = 0.07721

Step 4:

1 mol MO2 has 1 mol M and 2 moles O

m1 = (mol O * 16)/0.1338   m1 = 239.2 grams

1 mol M = 0.8632*239.2 = 206.48

0.90666m2 = 206.48  ⇒ m2 = 227.74 g

0.92832m3 = 206.48  ⇒ m3 = 222.42 g

Step 5: Calculate mass of O

Mass of O in compound A = 239.2 - 206.48 = 32.72 g

Mass of O in compound B = 227.74 - 206.48 = 21.26 g

Mass of O in compound C = 222.42- 206.48 = 15.94 g

Step 6: Calculate moles

Moles of O in compound A ≈ 2

⇒ MO2

Moles of O in compound B = 21.26 / 16 ≈ 1.33

⇒ M3O4

Moles of O compound C = 15.94 /16 ≈ 1 moles

⇒ MO

Step 7: Calculate molar mass

The mass of 1 mol metal is 206.48 grams  ⇒ molar mass ≈ 206.48 g/mol

The closest metal to this molar mass is lead (Pb)

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hope this helps

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