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kvv77 [185]
2 years ago
12

Consider 4.00 L of a gas at 365 mmHg and 20. ∘C . If the container is compressed to 2.80 L and the temperature is increased to 3

0. ∘C , what is the new pressure, P2 , inside the container? Assume no change in the amount of gas inside the cylinder.
Chemistry
1 answer:
stealth61 [152]2 years ago
6 0

This is an exercise in<u> the General Combined Gas Law</u>.

To start solving this exercise, we obtain the following data:

<h3>Data:</h3>
  • V₁ = 4.00 l
  • P₁ = 365 mmHg
  • T₁ = 20 °C + 273 = 293 K
  • V₂ = 2,80 l
  • T₂ = 30 °C + 273 = 303 K
  • P₂ = ¿?

We apply the following formula:

  • P₁V₁T₂=P₂V₂T₁     ⇒  General formula

Where:

  • P₁=Initial pressure
  • V₁=Initial volume
  • T₂=end temperature
  • P₂=end pressure
  • T₂=end temperature
  • V₁=Initial temperature

We clear for final pressure (P2)

\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{P_{1}V_{1}T_{2}}{V_{2}T_{1}} \ \ \to \ \ \ Formula \end{gathered}$}

We substitute our data into the formula:

\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{(365 \ mmHg)(4.00 \not{l})(303 \not{K})}{(2.80 \not{l})(293\not{K})}  \end{gathered}$}

\large\displaystyle\text{$\begin{gathered}\sf P_{2}=\frac{442380 \ mmHg}{ 820.4 }  \end{gathered}$}

\boxed{\large\displaystyle\text{$\begin{gathered}\sf P_{2}=539.224 \ mmHg \end{gathered}$}}

Answer: The new canister pressure is 539.224 mmHg.

<h2>{ Pisces04 }</h2>
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Natural gas is stored in a spherical tank at a temperature of 13°C. At a given initial time, the pressure in the tank is 117 kPa
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Answer:

1.  the absolute pressure in the tank before filling = 217 kPa

2. the absolute pressure in the tank after filling = 312 kPa

3. the ratio of the mass after filling M2 to that before filling M1 = 1.44

The correct relation is option c (\frac{M_{2} }{M_{1} } = \frac{P_{2} T_{1} }{P_{1} T_{2} })

Explanation:

To find  -

1. What is the absolute pressure in the tank before filling?

2. What is the absolute pressure in the tank after filling?

3. What is the ratio of the mass after filling M2 to that before filling M1 for this situation?

As we know that ,

Absolute pressure = Atmospheric pressure + Gage pressure

So,

Before filling the tank :

Given - Atmospheric pressure = 100 kPa ,  Gage pressure = 117 kPa

⇒Absolute pressure ( p1 )  = 100 + 117 = 217 kPa

Now,

After filling the tank :

Given - Atmospheric pressure = 100 kPa ,  Gage pressure = 212 kPa

⇒Absolute pressure (p2)  = 100 + 212= 312 kPa

Now,

As given, volume is the same before and after filling,

i.e. V_{1} = V_{2}

As we know that, P ∝ M

⇒ \frac{p_{1} }{p_{2} } = \frac{m_{1} }{m_{2} }

⇒\frac{m_{2} }{m_{1} } = \frac{p_{2} }{p_{1} }

⇒\frac{m_{2} }{m_{1} } = \frac{312 }{217 } = 1.4378 ≈ 1.44

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As V is constant

⇒ P ∝ MT

⇒\frac{P}{T} ∝ M

⇒\frac{M_{2} }{M_{1} } = \frac{P_{2} T_{1} }{P_{1} T_{2} }

So, The correct relation is c option.

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