1M KCl will require 25 mL to generate 100 mL of 0.25M KCl.
Molarity of a solution is defined as number of moles of solute present in 1000 mL of the solution.

So molarity is inversely proportional to the volume of the solution.
As solution is diluted. Molarity of the solution decreases.
1M of KCl means 1 mole of KCl in 1000 mL of the solution.
1M KCl is four times as concentrated as 0.25M KCl.
Therefore, to make 100 mL of 0.25M will require
of 1M KCl diluted to 100 mL of distilled water.
Easy alternative: Dilution formula

Where
are volume and concentration of first solution
and
are of second solution.

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