Answer : The correct option is, +91 kJ/mole
Solution :
The balanced cell reaction will be,
Here copper (Cu) undergoes oxidation by loss of electrons, thus act as anode. Lead (Pb) undergoes reduction by gain of electrons and thus act as cathode.
First we have to calculate the standard electrode potential of the cell.
![E^0_{[Pb^{2+}/Pb]}=-0.13V](https://tex.z-dn.net/?f=E%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D%3D-0.13V)
![E^0_{[Cu^{2+}/Cu]}=+0.34V](https://tex.z-dn.net/?f=E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D%3D%2B0.34V)
![E^0_{cell}=E^0_{[Pb^{2+}/Pb]}-E^0_{[Cu^{2+}/Cu]}](https://tex.z-dn.net/?f=E%5E0_%7Bcell%7D%3DE%5E0_%7B%5BPb%5E%7B2%2B%7D%2FPb%5D%7D-E%5E0_%7B%5BCu%5E%7B2%2B%7D%2FCu%5D%7D)
Now we have to calculate the standard Gibbs free energy.
Formula used :
where,
= standard Gibbs free energy = ?
n = number of electrons = 2
F = Faraday constant = 96500 C/mole
= standard e.m.f of cell = -0.47 V
Now put all the given values in this formula, we get the Gibbs free energy.
Therefore, the standard Gibbs free energy is +91 kJ/mole
A way of building knowledge about the world around us through observation and experimentation.
The coefficients in a chemical equation represent the molar ratio of the substances.
For example, if an equation says 2H2 + O2 ⇒ 2H2O, it means
2 moles of H2 + 1 mol of O2 ⇒ 2 moles of H2O.
Answer:
The correct answer is in an exothermic reaction the energy of the product is less than the energy of the reactants.
Explanation:
Exothermic reaction is a type of reaction that generates heat.As a result in case of an exothermic reaction the energy of the reactant is more than the energy of the product.
That"s why the enthalpy change in an exothermic reaction is always positive .
Answer:
Li(s) + H20(l) --> LiOH(aq) + H(g)
Explanation:
it is already balanced
