A 25. 0-ml sample of 1. 00 mnh3is titrated with 0. 15 mhcl. what is the ph of the solution after 15. 00 ml of acid have been add
1 answer:
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Answer : The correct option is, (D) 89.39 KJ/mole
Explanation :
First we have to calculate the moles of HCl and NaOH.
The balanced chemical reaction will be,
From the balanced reaction we conclude that,
As, 1 mole of HCl neutralizes by 1 mole of NaOH
So, 0.3562 mole of HCl neutralizes by 0.3562 mole of NaOH
Thus, the number of neutralized moles = 0.3562 mole
Now we have to calculate the mass of water.
As we know that the density of water is 1 g/ml. So, the mass of water will be:
The volume of water =
Now we have to calculate the heat absorbed during the reaction.
where,
q = heat absorbed = ?
= specific heat of water =
m = mass of water = 274 g
= final temperature of water = 325.8 K
= initial temperature of metal = 298 K
Now put all the given values in the above formula, we get:
Thus, the heat released during the neutralization = -31.84 KJ
Now we have to calculate the enthalpy of neutralization.
where,
= enthalpy of neutralization = ?
q = heat released = -31.84 KJ
n = number of moles used in neutralization = 0.3562 mole
The negative sign indicate the heat released during the reaction.
Therefore, the enthalpy of neutralization is, 89.39 KJ/mole