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1 year ago

What is responsible for the differences in chemical shift observed in carbon 4 in 4-fluoroheptane and carbon 4 in heptane?

1 answer:

4 0

The chemical shift of a given proton is decided specifically with the aid of interactions with the nearby electrons. The most necessary thing to recognize is that when electrons are subjected to an external magnetic field, they structure their own small prompted magnetic fields in opposition to the exterior field.

Consider the methane molecule ( CH4 ) in which the four equal protons have a chemical shift of 0.23 ppm (this is a price we can look up in any chemistry reference source). The valence electrons around the methyl carbon, when subjected to B0, generate their own very small triggered magnetic area that opposes B0 . This induced field, to a small however full-size degree, shields the close by protons from experiencing the full force of B0 , an impact regarded as local diamagnetic shielding. In different words, the methane protons do now not quite journey the full force of B0 - what they journey is known as Beff , or the high-quality field, which is slightly weaker than B0 due to the have an effect on of the close by electrons.

In nuclear magnetic resonance (NMR) spectroscopy, the chemical shift is the resonant frequency of an atomic nucleus relative to a preferred in a magnetic field. Often the position and range of chemical shifts are diagnostic of the shape of a molecule.

Learn more about chemical shifts here:

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Na+ and Cl- __________ ___________________________ Na+ and PO4 3- __________ ___________________________ Na+ and SO4 2- ________

bagirrra123 [75]

Answer:

For formation of a neutral ionic compound, the charges on cation and anion must be balanced. The cation is formed by loss of electrons by metals and anions are formed by gain of electrons by non metals.

The cations and anions being oppositely charged attract each other through strong coloumbic forces and form an ionic bond.

(1) Sodium is carrying +1 charge called as $Na^{+1}$ cation and chloride $Cl^{-1}$ is an anion carrying -1 charge. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral $NaCl$ .

(2) Sodium is carrying +1 charge called as $Na^{+1}$ cation and phosphate $PO_4^{-3}$ is an anion carrying -3 charge. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral $Na_3PO_4$ .

(3) Sodium is carrying +1 charge called as $Na^{+1}$ cation and sulfate $SO_4^{-2}$ is an anion carrying -2 charge. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral $Na_2SO_4$ .

(4) Sodium is carrying +1 charge called as $Na^{+1}$ cation and carbonate $CO_3^{-2}$ is an anion carrying -2 charge. Thus they combine and their oxidation states are exchanged and written in simplest whole number ratios to give neutral $Na_2CO_3$ .

(5) Potassium is carrying +1 charge called as $K^{+1}$ cation and chloride $Cl^{-1}$ is an anion carrying -1 charge. They form $KCl$ .

(6) Potassium is carrying +1 charge called as $K^{+1}$ cation and phosphate $PO_4^{-3}$ is an anion carrying -3 charge. They form $K_3PO_4$ .

(7) Potassium is carrying +1 charge called as $K^{+1}$ cation and sulfate $SO_4^{-2}$ is an anion carrying -2 charge. They form $K_2SO_4$ .

(8) Potassium is carrying +1 charge called as $K^{+1}$ cation and carbonate $CO_3^{-2}$ is an anion carrying -2 charge. They form $K_2CO_3$ .

(9) Calcium is carrying +2 charge called as $Ca^{+2}$ cation and chloride $Cl^{-1}$ is an anion carrying -1 charge. They form $CaCl_2$ .

(10) Calcium is carrying +2 charge called as $Ca^{+2}$ cation and phosphate $PO_4^{-3}$ is an anion carrying -3 charge. They form $Ca_3(PO_4)_2$ .

(11) Calcium is carrying +2 charge called as $Ca^{+2}$ cation and sulfate $SO_4^{-2}$ is an anion carrying -2 charge. They form $CaSO_4$ .

(12) Calcium is carrying +2 charge called as $Ca^{+2}$ cation and carbonate $CO_3^{-2}$ is an anion carrying -2 charge. They form $CaCO_3$ .

(13) Ammonium ion is carrying +1 charge called as $NH_4^{+1}$ cation and chloride $Cl^{-1}$ is an anion carrying -1 charge. They form $NH_4Cl$ .

(14) Ammonium ion is carrying +1 charge called as $NH_4^{+1}$ cation and phosphate $PO_4^{-3}$ is an anion carrying -3 charge. They form $NH_4_3PO_4$ .

(15) Ammonium ion is carrying +1 charge called as $NH_4^{+1}$ cation and sulfate $SO_4^{-2}$ is an anion carrying -2 charge. They form $NH_4_2SO_4$ .

(16) Ammonium ion is carrying +1 charge called as $NH_4^{+1}$ cation and carbonate $CO_3^{-2}$ is an anion carrying -2 charge. They form $NH_4_2CO_3$ .

(17) Iron is carrying +3 charge called as $Fe^{+3}$ cation and chloride $Cl^{-1}$ is an anion carrying -1 charge. They form $FeCl_3$ .

(18) Iron is carrying +3 charge called as $Fe^{+3}$ cation and phosphate $PO_4^{-3}$ is an anion carrying -3 charge. They form $FePO_4$ .

(19) Iron is carrying +3 charge called as $Fe^{+3}$ cation and sulfate $SO_4^{-2}$ is an anion carrying -2 charge. They form $Fe_2(SO_4)_3$ .

(20) Iron is carrying +3 charge called as $Fe^{+3}$ cation and carbonate $CO_3^{-2}$ is an anion carrying -2 charge. They form $Fe_2(CO_3)_3$ .

7 0

2 years ago

What changes would occur at a molecular level if a liquid is placed in cool conditions?

Dafna1 [17]

Answer: Option (C) is the correct answer.

Explanation:

Movement of particles in a substance is responsible for change in state of the substance or matter.

This means that more is the motion of particles more will be their kinetic energy.

Also, kinetic energy is directly proportional to temperature.

K.E = $\frac{3}{2}kT$

So, less is the temperature of an object or substance less will be be the motion of its particles. Therefore, molecules will come closer to each other and state of substance will change from liquid to solid.

Thus, we can conclude that the motion of the molecules would decrease at a molecular level if a liquid is placed in cool conditions.

6 0

2 years ago

Potassium (K) and calcium fluoride (CaF2) can both be classified as (Please help)

nasty-shy [4]

Potassium and calcium fluoride are both metals

8 0

2 years ago

When doing a recrystallization what observations would prompt you to perform a hot filtration?

KATRIN_1 [288]

Answer is: because dissolved compounds can crystallizing from solution during filtration and forming crystals on the filter paper or funnel.
Recrystallization is a technique used to purify chemicals by dissolving both impurities and a compound in an appropriate solvent, either compound or impurities can be removed from the solution, leaving the other behind.

3 0

2 years ago

Read 2 more answers

How many moles of Al are needed to react completely with 1.2 moles of Fe0

DIA [1.3K]

0.8 moles

3 moles of feO gives you 2 moles of Al and 1.2 of your moles should give you 1.2 divided by 3*2 so it equals 0.80 moles

Right?

7 0

2 years ago