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alina1380 [7]
2 years ago
6

What is responsible for the differences in chemical shift observed in carbon 4 in 4-fluoroheptane and carbon 4 in heptane?

Chemistry
1 answer:
Papessa [141]2 years ago
4 0

The chemical shift of a given proton is decided specifically with the aid of interactions with the nearby electrons. The most necessary thing to recognize is that when electrons are subjected to an external magnetic field, they structure their own small prompted magnetic fields in opposition to the exterior field.

Consider the methane molecule ( CH4 ) in which the four equal protons have a chemical shift of 0.23 ppm (this is a price we can look up in any chemistry reference source). The valence electrons around the methyl carbon, when subjected to B0, generate their own very small triggered magnetic area that opposes  B0 . This induced field, to a small however full-size degree, shields the close by protons from experiencing the full force of  B0 , an impact regarded as local diamagnetic shielding. In different words, the methane protons do now not quite journey the full force of  B0  - what they journey is known as  Beff , or the high-quality field, which is slightly weaker than  B0  due to the have an effect on of the close by electrons.

In nuclear magnetic resonance (NMR) spectroscopy, the chemical shift is the resonant frequency of an atomic nucleus relative to a preferred in a magnetic field. Often the position and range of chemical shifts are diagnostic of the shape of a molecule.

Learn more about chemical shifts here:

brainly.com/question/4289021

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What is the boiling point of cyclohexane at 620 mmhg? can you show calculations?
Anton [14]

 Boiling point of cyclohexane at 620 mm hg?  

Standard atmospheric pressure is 760 mm Hg. Boiling point at 760 mm= 80.74˚C  

A liquid boils when its vapor pressure is equal to the atmospheric pressure. The vapor pressure of a liquid is proportional the absolute temperature of the liquid.  

As the atmospheric pressure decreases, less vapor pressure is needed to cause the liquid to boil. Less vapor pressure means lower temperature.  

The boiling point of cyclohexane at 620 mm Hg is less than 80.74˚C



TRY THAT OR THIS

 

271.78

7 0
3 years ago
Read 2 more answers
What is the empirical formula of a molecule containing 65.5% carbon, 5.5% hydrogen, and 29.0% oxygen?
rusak2 [61]

Answer:

The empirical formula is C3H3O

Explanation:

Step 1: Data given

Suppose the mass of the molecule = 100 grams

The molecule contains:

65.5 % Carbon = 65.5 grams

5.5 % Hydrogen = 5.5 grams

29.0% Oxygen = 29.0 grams

Molar mass of C = 12 g/mol

Molar mass of H = 1.01 g/mol

Molar mass of O = 16 g/mol

Step 2: Calculate moles

Moles = mass / molar mass

Moles C = 65.5 grams / 12 g/mol = 5.46 moles

Moles H = 5.5 / 1.01 g/mol = 5.45 moles

Moles O = 29.0 grams / 16 g/mol = 1.8125 moles

Step 3: Calculate mol ratio

We divide by the smallest amount of moles

C: 5.46 / 1.8125 = 3

H = 5.45 / 1.8125 = 3

O = 1.8125/1.8125 = 1

The empirical formula is C3H3O

8 0
3 years ago
2. Metric Conversion: Which units are equivalent (the same) as 75g? (Pick 3)
kogti [31]

Answer:

0.075 kg

750 dg

7.5 dag

Explanation:

1 kg = 1000 g

So, 0.075 kg = (0.075 × 1000)g = 75 g

1 dg = 0.1 g

So, 750 dg = (750 × 0.1) g = 75 g

1 dag = 10 g

So, 7.5 dag = (7.5 × 10) g = 75 g

5 0
3 years ago
Ammonia has been studied as an alternative "clean" fuel for internal combustion engines, since its reaction with oxygen produces
Brilliant_brown [7]

Answer:

0.364

Explanation:

Let's do an equilibrium chart for the reaction of combustion of ammonia:

2NH₃(g) + (3/2)O₂(g) ⇄ N₂(g) + 3H₂O(g)

4.8atm 1.9atm 0 0 Initial

-2x -(3/2)x +x +3x Reacts (stoichiometry is 2:3/2:1:3)

4.8-2x 1.9-(3/2)x x 3x Equilibrium

At equilibrium the velocity of formation of the products is equal to the velocity of the formation of the reactants, thus the partial pressures remain constant.

If pN₂ = 0.63 atm, x = 0.63 atm, thus, at equilibrium

pNH₃ = 4.8 - 2*0.63 = 3.54 atm

pO₂ = 1.9 -(3/2)*0.63 = 0.955 atm

pH₂O = 3*0.63 = 1.89 atm

The pressure equilibrium constant (Kp) is calculated with the partial pressure of the gases substances:

Kp = [(pN₂)*(pH₂O)³]/[(pNH₃)²*(pO_2)^{3/2}]

Kp = [0.63*(1.89)³]/[(3.54)²*(0.955)^{3/2}]

Kp = 4.2533/11.6953

Kp = 0.364

7 0
3 years ago
What does the chemical formula of a molecule determine?
blsea [12.9K]
Since table salt is an ionic compound, the formula implies that numbers of Na+<span> ions, and Cl</span>-<span> ions are the same in the solid. The subscript numbers in an empirical formula should have no common divisor. A </span>structural<span> formula reflects the bonding of atoms in a molecule or ion.

</span>
3 0
4 years ago
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