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1 year ago

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Question 6

1 answer:

Naily [24]1 year ago

5 0

A British thermal unit (BTU) is defined as the amount of heat required to raise the temperature of 1 pound of water by 1 degree Fahrenheit. To calculate the temperature of a water sample from the BTUs applied to it, you must know the weight of the water and its starting temperature. You can measure the weight of the water using a scale, and the temperature using a Fahrenheit thermometer. Once you have that information, calculating the temperature of the water after applying a known number of BTUs of heat is easy.

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Imagine the reaction A + B LaTeX: \Longleftrightarrow⟺ C + D proceeds at room temperature (25 °C) and is determined to have a re

Wittaler [7]

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0.2 kcal/mol is the value of $\Delta G$ for this reaction.

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The formula used for is:

$\Delta G_{rxn}=\Delta G^o+RT\ln Q$

$\Delta G^o=-RT\ln K$

where,

$\Delta G_{rxn}$ = Gibbs free energy for the reaction

$\Delta G_^o$ = standard Gibbs free energy

R =Universal gas constant

T = temperature

Q = reaction quotient

k = Equilibrium constant

We have :

Reaction quotient of the reaction = Q = 46

Equilibrium constant of reaction = K = 35

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R = 1.987 cal/K mol

$\Delta G_{rxn}=-RT\ln K+RT\ln Q$

$=-1.987 cal/K mol\times 298 K\ln [35]+1.987 cal/K mol\times 298K\times \ln [46]$

$=-2,105.21 cal/mol+2,267.04 cal/mol=161.82 cal/mol=0.16182 kcal/mol\approx 0.2 kcal/mol$

1 cal = 0.001 kcal

0.2 kcal/mol is the value of $\Delta G$ for this reaction.

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