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NemiM [27]
1 year ago
9

A voltaic cell has one half-cell with a Cu bar in a 1.00 M Cu²⁺ salt, and the other half-cell with a Cd bar in the same volume o

f a 1.00 M Cd²⁺ salt.(a) Find E°cell ΔG°, and K.
Chemistry
1 answer:
Verizon [17]1 year ago
6 0

The E^o_{cell} of the voltaic cell is 0.743 V. The ΔG°of the given cell is -143.377 kJ and K is 1.35 × 10²⁵

<h3>What is a voltaic cell?</h3>

A voltaic cell often called a galvanic cell, is an electrochemical device that produces electricity through spontaneous redox processes.

It is divided into two distinct half-cells. A half-cell is made up of an electrode (a metal strip, M) dissolved in a solution containing Mn⁺ ions. M can be any metal.

A wire from one electrode to the other connects the two half-cells. Additionally, a salt bridge links the two half-cells.

To solve the question, we need to write the equations of two half-cells

At the anode, oxidation occurs

Cd(s) \rightarrow Cd^{2+}(aq) + 2e^-

E° = -0.403 V

At the cathode, reduction occurs

Cu^{2+}(aq) + 2e^- \rightarrow Cu(s)

E° = 0.34 V

Overall reaction:

Cd(s) + Cu^{2+}(aq) \rightarrow Cd^{2+}(aq) + Cu(s)

We know

E^o_{cell} = E^o_{cathode} - E^o_{anode}

= 0.34 -(-0.403) = 0.743 V

Also,

ΔG° = -nFE^o_{cell}

Where, n = no of electrons gained or lost

F = Faraday constant

E^o_{cell} = standard potential

ΔG° = -2×96485×0.743 = -143376.71 J = -143.377 kJ

Also,

ΔG° = -RTlnK

-143.377 = -8.314 × 10-3 × 298 × lnK

lnK = 57.87

K = 1.35 × 10²⁵

Hence, The E^o_{cell} of the voltaic cell is 0.743 V. The ΔG°of the given cell is -143.377 kJ and K is 1.35 × 10²⁵

Learn more about Voltaic cell:

brainly.com/question/4430225

#SPJ4

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nataly862011 [7]

Answer:

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<em></em>

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-2.7× (0.660 = 2.00x10³ × Ctry  + 1.12x10⁴ × Ctyr) =

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-1.561 = -28740×Ctyr

<em>5.43x10⁻⁵ dm³mol⁻¹= Ctyr</em>

Replacing this value in (1) or (2) it is possible to find Ctry, that is:

<em>2.58x10⁻⁵ dm³mol⁻¹= Ctry</em>

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