Use Hess's law to calculate AG° rxn using the following information.

The reaction of NO2 with ozone produces NO3 in a second-order reaction overall.

Brilliant_brown [7]

Answer : The rate of reaction is,

$Rate=4.77\times 10^{-19}M/s$

The appearance of $NO_3$ is, $4.77\times 10^{-19}M/s$

Explanation :

The general rate of reaction is,

$aA+bB\rightarrow cC+dD$

Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.

The expression for rate of reaction will be :

$\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}$

$\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}$

$\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}$

$\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}$

$Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}$

From this we conclude that,

In the rate of reaction, A and B are the reactants and C and D are the products.

a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.

The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.

The given rate of reaction is,

$NO_2(g)+O_3(g)\rightarrow NO_3(g)+O_2(g)$

The rate law expression will be:

$Rate=k[NO_2][O_3]$

Given:

Rate constant = $k=1.69\times 10^{-4}M^{-1}s^{-1}$

$[NO_2]$ = $1.77\times 10^{-8}M$

$[O_3]$ = $1.59\times 10^{-7}M$

$Rate=k[NO_2][O_3]$

$Rate=(1.69\times 10^{-4})\times (1.77\times 10^{-8})\times (1.59\times 10^{-7})$

$Rate=4.77\times 10^{-19}M/s$

The expression for rate of appearance of $NO_3$ :

$\text{Rate of reaction}=\text{Rate of appearance of }NO_3=+\frac{d[NO_3]}{dt}$

As, $\text{Rate of reaction}=4.77\times 10^{-19}M/s$

So, $\text{Rate of appearance of }NO_3=+\frac{d[NO_3]}{dt}=4.77\times 10^{-19}M/s$

Thus, the appearance of $NO_3$ is, $4.77\times 10^{-19}M/s$

7 0

3 years ago

What is science about?

Olin [163]

Answer:

Science is the study of the nature and behavior of natural things and the knowledge that we obtain about them. ... A science is a particular branch of science such as physics, chemistry, or biology. Physics is the best example of a science which has developed strong, abstract theories.

Explanation:

8 0

2 years ago

Read 2 more answers

What is true about an element

stich3 [128]

Answer:

made from ine atom

Explanation:

one atom

5 0

2 years ago

Calculate the energy required to produce 7.00 mol Cl2O7 on the basis of the following balanced equation. 2Cl2(g) + 7O2(g) + 130

KatRina [158]

Explanation:

As the given chemical reaction equation is as follows.

$2Cl_{2}(g) + 7O_{2}(g) + 130 kcal \rightarrow 2Cl_{2}O_{7}(g)$

Also, it is given that for 2 moles the energy required is 130 kcal. This means that energy required for 1 mole is calculated as follows.

1 mole = $\frac{130 kcal}{2}$

= 65 kcal

Hence, energy required for 7 moles will be calculated as follows.

Energy required = $7 \times 65 kcal$

= 455 kcal

Thus, we can conclude that energy required to produce 7.00 mol $Cl_{2}O_{7}$ on the basis of given reaction is 455 kcal.

3 0

3 years ago

A bulb is found to weigh 5.76 grams more when filled with air at 298 K and 1.00 atmosphere pressure than when it is evacuated. W

garik1379 [7]

Answer:

Subtract water vapor pressure from total pressure to get partial pressure of gas A: PA=1.03 atm- 1 atm=0.03 atm.

What is the total pressure of the gases at 298 K?

98.8 kPa

A sample of nitrogen gas is bubbled through water at 298 K and the volume collected is 250 mL. The total pressure of the gas, which is saturated with water vapour, is found to be 98.8 kPa at 298 K.

The total pressure of a mixture of gases can be defined as the sum of the pressures of each individual gas: Ptotal=P1+P2+… +Pn. + P n . The partial pressure of an individual gas is equal to the total pressure multiplied by the mole fraction of that gas.

How do you find the partial pressure of water in air?

e is vapor pressure Rv = R∗/Mv = 461.5Jkg−1K−1 and Mv = 18.01gmol−1, ϵ = Mv/Md = 0.622. The vapor pressure is the partial pressure of the water vapor. where es is in Pascals and T is in Celsius.

ExpHow do you find the pressure of h2?

For the high pressures in which hydrogen gas is often stored, the van der Waals equation can be used. It is P+a(n/V)^2=nRT. For diatomic hydrogen gas, a=0.244atm L^2/mol^2 and b=0.0266L/mol.lanation:

6 0

2 years ago