Answer:
The value of is 0.02495.
Explanation:
Initial concentration of gas = 0.675 M
Initial concentration of gas = 0.973 M
Equilibrium concentration of mustard gas = 0.35 M
initially
0.675 M 0.973 M 0
At equilibrium ;
(0.675-0.35) M (0.973-2 × 0.35) M 0.35 M
The equilibrium constant is given as :
The relation between and are :
where,
= equilibrium constant at constant pressure = ?
= equilibrium concentration constant =14.45
R = gas constant = 0.0821 L⋅atm/(K⋅mol)
T = temperature = 20.0°C =20.0 +273.15 K=293.15 K
= change in the number of moles of gas = [(1) - (1 + 2)]=-2
Now put all the given values in the above relation, we get:
The value of is 0.02495.
Answer:
a. Endothermic
b. 26.37kJ/mol
Explanation:
a. As we can see, the temperature of the water is decreasing when the reaction is occurring, that means the reaction is absorbing heat and is endothermic
b. To find the enthalpy we must find the change in heat when 12.1g of KCl are dissolved. Using the equation:
Q = -m*ΔT*C
<em>Where Q is change in heat</em>
<em>m the mass of solution (250g + 12.1g = 262.1g)</em>
<em>ΔT is change in heat (17.1°C - 21.0°C = -3.9°C)</em>
<em>And C is specific heat of the solution (4.184J/g°C assuming is the same than the specific heat of water).</em>
<em />
Replacing:
Q = -262.1g*-3.9°C*4.184J/g°C
Q = 4277J = 4.28kJ
As reaction enthalpy is the change in heat per mole of reaction, we must find the moles of 12.1g of KCl:
<em>Moles KCl -Molar mass: 74.55g/mol-:</em>
12.1g KCl * (1 mol / 74.55g) = 0.1623 moles KCl
The reaction enthalpy us:
4.28kJ / 0.1623mol = }
<h3>26.37kJ/mol</h3>
<em />
The charge on an electron is ~
" - " symbol is used to show that its negative.
TiCl₄+2H₂O⇔TiO₂+4HCl
The coefficient for titanium tetrachloride = 1
<h3>Further explanation
</h3>
Equalization of chemical reactions can be done using variables. Steps in equalizing the reaction equation:
1. gives a coefficient on substances involved in the equation of reaction such as a, b, or c, etc.
2. make an equation based on the similarity of the number of atoms where the number of atoms = coefficient × index (subscript) between reactant and product
3. Select the coefficient of the substance with the most complex chemical formula equal to 1
Reaction
TiCl₄+H₂O⇔TiO₂+HCl
give coefficient
TiCl₄+aH₂O⇔bTiO₂+cHCl
Ti, left=1, right=b⇒b=1
Cl, left=4, right=c⇒c=4
H, left=2a, right=c⇒2a=c⇒2a=4⇒a=2
O, left=a, right=2b⇒a=2b⇒2=2.1⇒match
Balanced equation :
TiCl₄+2H₂O⇔TiO₂+4HCl