A) Temperature does not affect reaction rate
Answer:
![[Ag^{+}]=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
Explanation:
Given:
[AgNO3] = 0.20 M
Ba(NO3)2 = 0.20 M
[K2CrO4] = 0.10 M
Ksp of Ag2CrO4 = 1.1 x 10^-12
Ksp of BaCrO4 = 1.1 x 10^-10

![Ksp=[Ba^{2+}][CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BBa%5E%7B2%2B%7D%5D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.2\times 10^{-10}=(0.20)[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=1.2%5Ctimes%2010%5E%7B-10%7D%3D%280.20%29%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![[CrO_{4}^{2-}]=\frac{1.2\times 10^{-10}}{(0.20)}= 6.0\times 10^{-10}](https://tex.z-dn.net/?f=%5BCrO_%7B4%7D%5E%7B2-%7D%5D%3D%5Cfrac%7B1.2%5Ctimes%2010%5E%7B-10%7D%7D%7B%280.20%29%7D%3D%206.0%5Ctimes%2010%5E%7B-10%7D)
Now,

![Ksp=[Ag^{+}]^{2}[CrO_{4}^{2-}]](https://tex.z-dn.net/?f=Ksp%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5BCrO_%7B4%7D%5E%7B2-%7D%5D)
![1.1\times 10^{-12}=[Ag^{+}]^{2}](6.0\times 10^{-10})](https://tex.z-dn.net/?f=1.1%5Ctimes%2010%5E%7B-12%7D%3D%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%286.0%5Ctimes%2010%5E%7B-10%7D%29)
![[Ag^{+}]^{2}]=\frac{1.1\times 10^{-12}}{(6.0\times 10^{-10})}= 1.8\times 10^{-3}](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5D%3D%5Cfrac%7B1.1%5Ctimes%2010%5E%7B-12%7D%7D%7B%286.0%5Ctimes%2010%5E%7B-10%7D%29%7D%3D%201.8%5Ctimes%2010%5E%7B-3%7D)
![[Ag^{+}]=\sqrt{1.8\times 10^{-3}}=4.2\times 10^{-2}M](https://tex.z-dn.net/?f=%5BAg%5E%7B%2B%7D%5D%3D%5Csqrt%7B1.8%5Ctimes%2010%5E%7B-3%7D%7D%3D4.2%5Ctimes%2010%5E%7B-2%7DM)
So, BaCrO4 will start precipitating when [Ag+] is 4.2 x 1.2^-2 M
Answer:
[Cl2] equilibrium = 0.0089 M
Explanation:
<u>Given:</u>
[SbCl5] = 0 M
[SbCl3] = [Cl2] = 0.0546 M
Kc = 1.7*10^-3
<u>To determine:</u>
The equilibrium concentration of Cl2
<u>Calculation:</u>
Set-up an ICE table for the given reaction:

I 0 0.0546 0.0546
C +x -x -x
E x (0.0546-x) (0.0546-x)
![Kc = \frac{[SbCl3][Cl2]}{[SbCl5]}\\\\1.7*10^{-3} =\frac{(0.0546-x)^{2} }{x} \\\\x = 0.0457 M](https://tex.z-dn.net/?f=Kc%20%3D%20%5Cfrac%7B%5BSbCl3%5D%5BCl2%5D%7D%7B%5BSbCl5%5D%7D%5C%5C%5C%5C1.7%2A10%5E%7B-3%7D%20%3D%5Cfrac%7B%280.0546-x%29%5E%7B2%7D%20%7D%7Bx%7D%20%5C%5C%5C%5Cx%20%3D%200.0457%20M)
The equilibrium concentration of Cl2 is:
= 0.0546-x = 0.0546-0.0457 = 0.0089 M
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Answer: b. The waste generated is hazardous and must be disposed of.
c. Nuclear material can be spilled into the ocean if reactors are near the coast.
d. A large amount of cold water is generated, which must be stored somewhere.
Explanation:
The main environmental costs for produced during the nuclear power plant consists of procurement of fuel and the thermal load is also produced with cold water discharge in the sea. This can contaminate the sea, hence, must be stored somewhere. The nuclear waste consists of radioactive substances which are hazardous for the environment. The nuclear based electricity does not produce carbon dioxide.