Answer:
P₂ ≅ 100 atm (1 sig. fig. based on the given value of P₁ = 90 atm)
Explanation:
Given:
P₁ = 90 atm P₂ = ?
V₁ = 18 Liters(L) L₂ = 12 Liters(L)
=> decrease volume => increase pressure
=> volume ratio that will increase 90 atm is (18L/12L)
T₁ = 272 Kelvin(K) T₂ = 274 Kelvin(K)
=> increase temperature => increase pressure
=> temperature ratio that will increase 90 atm is (274K/272K)
n₁ = moles = constant n₂ = n₁ = constant
P₂ = 90 atm x (18L/12L) x (274K/272K) = 135.9926471 atm (calculator)
By rule of sig. figs., the final answer should be rounded to an accuracy equal to the 'measured' data value having the least number of sig. figs. This means P₂ ≅ 100 atm based on the given value of P₁ = 90 atm.
Answer:
The reaction is not spontaneous in the forward direction, but in the reverse direction.
Explanation:
<u>Step 1: </u>Data given
H2(g) + I2(g) ⇌ 2HI(g) ΔG° = 2.60 kJ/mol
Temperature = 25°C = 25+273 = 298 Kelvin
The initial pressures are:
pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
<u>Step 2</u>: Calculate ΔG
ΔG = ΔG° + RTln Q
with ΔG° = 2.60 kJ/mol
with R = 8.3145 J/K*mol
with T = 298 Kelvin
Q = the reaction quotient → has the same expression as equilibrium constant → in this case Kp = [p(HI)]²/ [p(H2)] [p(I2)]
with pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
Q = (3.10²)/(1.5*1.75)
Q = 3.661
ΔG = ΔG° + RTln Q
ΔG = 2600 J/mol + 8.3145 J/K*mol * 298 K * ln(3.661)
ΔG =5815.43 J/mol = 5.815 kJ/mol
To be spontaneous, ΔG should be <0.
ΔG >>0 so the reaction is not spontaneous in the forward direction, but in the reverse direction.
Answer:
They are held together by hydrogen bonds
Explanation:
Hydrogen bonds are special dipole-dipole attractions between polar molecules in which a hydrogen atom is directly joined to a highly electronegative atom(oxygen or nitorgen or fluorine).
Such molecules includes water, alkanoic acids, ammonia and amines.
A hydrogen nucleus has a high concentration of positive charge. The bond is actually an electrostatic attraction between the hydrogen atom of one molecule and the electronegative atom(O or N or F).
Hydrogen bonds are very effective in binding molecules into larger units. Most substances that joins with hydrogen bonds have a higher boiling point and lower volatility.
This is why we have a strong intermolecular bond between water molecules.
Mass is the amount of matter in an object. Density is the degree of compactness of a substance
