Boyle’s law gives the relationship between pressure and volume of gases. It states that at constant temperature the pressure of gas is inversely proportional to volume of gas.
PV = k
Where P is pressure V is volume and k is constant
P1V1 = P2V2
Parameters at STP are on the left side and parameters for the second instance are on the right side of the equation
P1 - standard pressure - 1.0 atm
Substituting the values in the equation
1.0 atm x 5.00 L = P x 15.0 L
P = 0.33 atm
New pressure is 0.33 atm
Answer:
75 kJ/mol
Explanation:
The reactions occur at a rate, which means that the concentration of the reagents decays at a time. The rate law is a function of the concentrations and of the rate constant (k) which depends on the temperature of the reaction.
The activation energy (Ea) is the minimum energy that the reagents must have so the reaction will happen. The rate constant is related to the activation energy by the Arrhenius equation:
ln(k) = ln(A) -Ea/RT
Where A is a constant of the reaction, which doesn't depend on the temperature, R is the gas constant (8.314 J/mol.K), and T is the temperature. So, for two different temperatures, if we make the difference between the two equations:
ln(k1) - ln(k2) = ln(A) - Ea/RT1 - ln(A) + Ea/RT2
ln (k1/k2) = (Ea/R)*(1/T2 - 1/T1)
k1 = 8.3x10⁸, T1 = 142.0°C = 415 K
k2 = 6.9x10⁶, T2 = 67.0°C = 340 K
ln(8.3x10⁸/6.9x10⁶) = (Ea/8.314)*(1/340 - 1/415)
4.8 = 6.39x10⁻⁵Ea
Ea = 75078 J/mol
Ea = 75 kJ/mol
The relationship would be inversely proportional, meaning that as the volume increases, the pressure decreases, and the opposite is true as well, as the pressure increases, the volume decreases.
Yes it is possible because, olymorphismis when two or more crystal structures are possible for a material of given composition. Isomerismis when two or more polymer molecules or repeat units have the same composition, but different atomic arrangements.
