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3 years ago

Draw the resonance structures for (SCN)".

Chemistry

1 answer:

Phantasy [73]3 years ago

3 0

Answer : The resonance structure of $SCN$ is shown below.

Explanation :

Resonance structure : It is defined as when more than one Lewis structure can be drawn, the molecule or ion is said to have resonance.

Resonance is the concept where electrons (bonds) are delocalized over three or more atoms which cannot be depicted with one simple Lewis structure.

First we have to draw Lewis-dot structure.

Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule.

In the Lewis-dot structure the valance electrons are shown by 'dot'.

The given molecule is, $SCN$

As we know that sulfur has '6' valence electrons, carbon has '6' valence electrons and nitrogen has '5' valence electron.

Therefore, the total number of valence electrons in $SCN$ = 6 + 4 + 5 = 15

According to Lewis-dot structure, there are 7 number of bonding electrons and 8 number of non-bonding electrons.

In SCN, carbon atom is the central atom and sulfur and nitrogen are the neighboring atoms.

The resonance structure of $SCN$ is shown below.

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The molar mass is determined by measuring the freezing point depression of an aqueous solution. A freezing point of -5.20°C is r

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Answer:

The empirical formula is C2H4O3

The molecular formula is C4H8O6

The molar mass is 152 g/mol

Explanation:

The complete question is: An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of -5.20°C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.

Step 1: Data given

Mass % of Carbon = 31.57 %

Mass % of H = 5.30 %

Freezing point = -5.20 °C

10.56 grams of the compound dissolved in 25.0 grams of water

Kf water = 1.86 °C kg/mol

Step 2: Calculate moles of Carbon

Suppose 31.57% = 31.57 grams

moles C = mass C / Molar mass C

moles C = 31.57 grams / 12.0 g/mol = 2.63 moles

Step 3: Calculate moles of Hydrogen:

Moles H = 5.30 grams / 1.01 g/mol

moles H = 5.25 moles

Step 4: Calculate moles of Oxygen

Moles O = ( 100 - 31.57 - 5.30) / 16 g/mol

Moles O = 3.95 moles

Step 5: We divide by the smallest number of moles

C: 2.63 / 2.63 = 1 → 2

H: 5.25/2.63 = 2 → 4

O: 3.95/ 2.63 = 1.5 → 3

The empirical formula is C2H4O3

The molar mass of the empirical formula = 76 g/mol

Step 6: Calculate moles solute

Freezing point depression = 5.20 °C = m * 1.86

m = 5.20 / 1.86

m = 2.80 molal = 2.80 moles / kg

2.80 molal * 0.025 kg = 0.07 moles

Step 7: Calculate molar mass

Molar mass = mass / moles

Molar mass = 10.56 grams / 0.07 moles

Molar mass = 151 g/mol

Step 8: Calculate molecular formula

151 / 76 ≈ 2

We have to multiply the empirical formula by 2

2*(C2H4O3) = C4H8O6

The molecular formula is C4H8O6

The molar mass is 152 g/mol

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