Answer:
See explanation
Explanation:
For this question, we have to remember the effect of an atom with high <u>electronegativity</u> as "Br". If the "Br" atom is closer to the carboxylic acid group (COOH) we will have an <u>inductive effect</u>. Due to the electronegativity of Br, the electrons of the C-H bond would be to the Br, then this bond would be <u>weaker</u> and the compound will be more acid (because is easier to produce the hydronium ion
).
With this in mind, for A in the last compound, we have <u>2 Br atoms</u> near to the acid carboxylic group, so, we will have a high inductive effect, then the C-H would be weaker and we will have <u>more acidity</u>. Then we will have the compound with only 1 Br atom and finally, the last compound would be the one without Br atoms.
In B, the difference between the molecules is the <u>position</u> of the "Br" atom in the molecule. If the Br atom is closer to the acid group we will have a <u>higher inductive effect</u> and more <u>acidity</u>.
See figure 1
I hope it helps!
Answer: 1.24 × 10^25
Explanation:
× 
Using our knowledge in unit conversions, we know the mole units cancel each other out and all there's left is the atom unit. From here we can multiply the fractions and eventually we end with the number 124.0532 × 10^23
According to the scientific notation rules, the number to the left of the decimal cannot exceed 10 so we have to move the decimal to the left two spaces. With this change, we also have to change the exponent of the 10. Because we moved the decimal point two spaces to the left, that means we have 10^25.
Answer:
In this case, the system doesn't be affected by the pressure change. This means that nothing will happen
Explanation:
We can answer this question applying the Le Chatelier's Principle. It says that changes on pressure, volume or temperature of an equilibrium reaction will change the reaction direction until it returns to the equilibrium condition again.
The results of these changes can define as:
Changes on pressure: the reaction will move depending the quantity of moles on each side of the reaction
Changes on temperature: The reaction will move depending on if it's endothermic or exothermic
Changes on volume: The reaction will move depending the limit reagent and the quantity of moles on each side of the reaction
In the exercise, they mention a change on pressure of the system at constant temperature (that means the temperature doesn't change). As Le Chatelier Principle's says, we must analyze what happens if the pressure increase or decrease. If pressure increase the reaction will move on the side that have less quantity of moles, otherwise, if the pressure decreases the reaction will move to the side that have more quantity of moles. In this case, we can see that both sides of the equation have the same number of moles (2 for the reactants and 2 for the products). So, in this case, we can conclude that, despite the change on pressure (increase or decrease), nothing will happen.
Answer:
V = 134.5 L
Explanation:
Given data:
Number of moles of KClO₃ = 4 mol
Litters of oxygen produced at STP = ?
Solution:
Chemical equation:
2KClO₃ → 2KCl + 3O₂
Now we will compare the moles of KClO₃ with oxygen.
KClO₃ : O₂
2 : 3
4 ; 3/2×4 = 6 mol
Litters of oxygen at STP:
PV = nRT
V = nRT/P
V = 6 mol × 0.0821 atm.L/mol.K × 273 K / 1atm
V = 134.5 L / 1
V = 134.5 L