Pretend that you are the size of an atom, observing a reaction between a potassium atom and a fluorine atom. Write an account of
1 answer:
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Answer:
1 ) Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
2) ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
Explanation:
<u>1) To show that heat flows spontaneously from high temperature to low temperature </u>
example :
Pick two(2) solid metal blocks with varying temperatures ( i.e. one solid block is hot and the other solid block is cold )
Place both blocks for time (t ) in an insulated system to reduce heat loss or gain to or from the environment
Check the temperature of both blocks after time ( t ) it will be observed that both blocks will have same temperature after time t ( first law of thermodynamics )
Δs ( entropy change for hot block ) = - Q / th ( -ve shows heat lost to cold block )
Δs ( entropy change for cold block ) = Q / tc
∴ Total Δs = ΔSc + ΔSh
= Q/tc - Q/th
<u>2) Entropy change for Decomposition of mercuric oxide </u>
2HgO (s) → 2Hg(l) + O₂ (g)
Δs = positive
there is transition from solid to liquid and the melting point of mercury ( the point at which reaction will take place ) = 500⁰C
hence ΔSdecomposition = S⁻ Hg - S⁻ HgO =
Δh of reaction = 181.6 KJ
Temp = 500 + 273 = 773 k
hence ΔSdecomposition = Δh / Temp = ( 181.6 * 10^3 / 773 ) = 234.928 J/k
Explanation:
The weak intermolecular forces which can arise either between nucleus and electrons or between electron-electron are known as dispersion forces. These forces are also known as London dispersion forces and these are temporary in nature.
Therefore, more is the surface area occupied by the carbon chain more will be the dispersion forces present in it. Hence, less is the surface area occupied by a molecule less will be the dispersion forces present in it.
Hence, the given molecules are organized from largest to smallest dispersion forces as follows.
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