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NNADVOKAT [17]
3 years ago
13

Consider the following equilibrium: 4KO2(s) + 2H2O(g) 4KOH(s) + 3O2(g) Which of the following is a correct equilibrium expressio

n?
Chemistry
1 answer:
jeka57 [31]3 years ago
5 0
To be able to write correctly the equilibrium expression of a reaction, we need to know the balanced reaction and the phases of the substances in the reaction. When substances are solid, pure liquid they are not included in the expression. We do as follows:

<span>4KO2(s) + 2H2O(g) = 4KOH(s) + 3O2(g)

K = [O2]^3 / [H2O]^2</span>
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Answer: The hydroboration of an alkene occurs in TWO CONCERTED STEP which places the boron of the borane on the LESS SUBSTITUTED carbon of the double bond. The oxidizing agent then acts as a nucleophile, attacking the electrophilic BORON and resulting in the placement of a hydroxyl group on the attached carbon. Thus, the major product of the hydroboration oxidation reaction DOES NOT follow Markovnikov's rule.

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Hydroboration is defined as the process which allows boron to attain the octet structure. This involves a two steps pathway which leads to the production of alcohol.

--> The first step: this involves the initiation of the addittion of borane to the alkene and this proceeds as a concerted reaction because bond breaking and bond formation occurs at the same time.

--> The second step: this involves the addition of boron which DOES NOT follow Markovnikov's rule( that is, Anti Markovnikov addition of Boron). This is so because the boron adds to the less substituted carbon of the alkene, which then places the hydrogen on the more substituted carbon.

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