The difference between the calculated voltage (based on standard potentials) and the actual voltage required to cause electrolysis is called overvoltage.
<h3>Electrolysis </h3>
Electrolysis is the technique of causing a chemical change in a substance by passing an electric current through it. The substance either loses or gets an electron during the chemical transition (oxidation or reduction). The procedure is carried out in an electrolytic cell, a device made up of positive and negative electrodes that are kept apart and submerged in a solution with ions that are both positively and negatively charged. The chemical that needs to be converted might either be dissolved in the solution or could form the electrode. The negatively charged electrode (cathode) receives electrical current (i.e., electrons), which travels there and combines with the components of the solution to convert them (reduced).
Learn more about electrolysis here:
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When the first reaction equation is:
AgI(S) ↔ Ag+(Aq) + I-(Aq)
So, the Ksp expression = [Ag+][I-]
∴Ksp = [Ag+][I-] = 8.3 x 10^-17
Then the second reaction equation is:
Ag+(aq) + 2NH3(aq) ↔ Ag(NH3)2+
So, Kf expression = [Ag(NH3)2+] / [Ag+] [NH3]^2
∴Kf = [Ag(NH3)2+] /[Ag+] [NH3]^2 = 1.7 x 10^7
by combining the two equations and solve for Ag+:
and by using ICE table:
AgI(aq) + 2NH3 ↔ Ag(NH3)2+ + I-
initial 2.5 0 0
change -2X +X +X
Equ (2.5-2X) X X
so K = [Ag(NH3)2+] [I-] / [NH3]^2
Kf * Ksp = X^2 / (2.5-2X)
8.3 x 10^-17 * 1.7 x10^7 = X^2 / (2.5-2X) by solving for X
∴ X = 5.9 x 10^-5
∴ the solubility of AgI = X = 5.9 x 10^-5 M
Answer:
17.65 grams of O2 are needed for a complete reaction.
Explanation:
You know the reaction:
4 NH₃ + 5 O₂ --------> 4 NO + 6 H₂O
First you must know the mass that reacts by stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction). For that you must first know the reacting mass of each compound. You know the values of the atomic mass of each element that form the compounds:
- N: 14 g/mol
- H: 1 g/mol
- O: 16 g/mol
So, the molar mass of the compounds in the reaction is:
- NH₃: 14 g/mol + 3*1 g/mol= 17 g/mol
- O₂: 2*16 g/mol= 32 g/mol
- NO: 14 g/mol + 16 g/mol= 30 g/mol
- H₂O: 2*1 g/mol + 16 g/mol= 18 g/mol
By stoichiometry, they react and occur in moles:
- NH₃: 4 moles
- O₂: 5 moles
- NO: 4 moles
- H₂O: 6 moles
Then in mass, by stoichiomatry they react and occur:
- NH₃: 4 moles*17 g/mol= 68 g
- O₂: 5 moles*32 g/mol= 160 g
- NO: 4 moles*30 g/mol= 120 g
- H₂O: 6 moles*18 g/mol= 108 g
Now to calculate the necessary mass of O₂ for a complete reaction, the rule of three is applied as follows: if by stoichiometry 68 g of NH₃ react with 160 g of O₂, 7.5 g of NH₃ with how many grams of O₂ will it react?
mass of O₂≅17.65 g
<u><em>17.65 grams of O2 are needed for a complete reaction.</em></u>
Molar mass of sodium chloride is 22.99 g/mol (Na+) + 35.45 g/mol (Cl-) = x g/mol. Then take the mass of sodium chloride sample 5 grams and divide by molar mass to get the number of moles. Take this number and multiply it by Avogadro’s number (6.22*10^23 molecules/mol). You now have the amount of molecules in 5 grams of NaCl.
Answer:
false
Explanation:
It is called the periodic table because of the way the elements are arranged. You'll notice they're in rows and columns. The horizontal rows (which go from left to right) are called 'periods' and the vertical columns (going from up to down) are called 'groups'.
