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Aleksandr [31]
3 years ago
14

A fat is composed of long chains of carbon and hydrogen atoms. In a reaction with a strong base, a fat forms a soap and glycerol

. What is the empirical formula of a fat containing 77.60 % carbon, 11.45 % oxygen, and 10.95 % hydrogen? What is its molecular formula if its molecular mass is 1253 g/mol?
Chemistry
1 answer:
Nonamiya [84]3 years ago
4 0

Answer:

Empirical formula is C₉H₁₅O

Molecular formula = C₈₁H₁₃₅O ₉

Explanation:

Percentage of carbon = 77.60%

Percentage of oxygen = 11.45%

Percentage of hydrogen = 10.95%

Molecular weight = 1253 g/mol

Molecular formula = ?

Empirical formula = ?

Solution:

Number of gram atoms of C = 77.60 g /12g/mol =6.5

Number of gram atoms of O = 11.45 g / 16 g/mol = 0.72

Number of gram atoms of H = 10.95 g / 1.008 g/mol= 10.9

Atomic ratio:

C               :            H                 :    O

6.5/0.72   :       10.9/0.72         :   0.72/0.72

     9          :            15              :         1

C : H : O = 9 : 15 : 1

Empirical formula is C₉H₁₅O

Molecular formula:

Molecular formula = n (empirical formula)

n = molar mass of compound / empirical formula mass

n = 1253 / 139

n = 9

Molecular formula = n (empirical formula)

Molecular formula = 9 (C₉H₁₅O )

Molecular formula = C₈₁H₁₃₅O ₉

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\text{Glyceraldehyde3-phosphate }+NAD^++HPO_4^{2-}\rightarrow \text{1,3-Biphosphoglycerate }+NADH+H^+

The equation used to Gibbs free energy of the reaction follows:

\Delta G=\Delta G^o+RT\ln K_{eq}

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\Delta G = free energy of the reaction

\Delta G^o = standard Gibbs free energy = 6.3 kJ/mol = 6300 J/mol  (Conversion factor: 1kJ = 1000J)

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[273+25]K=298K  

K_{eq} = Ratio of concentration of products and reactants = \frac{[BPG][NaDH][H^+]}{[G_3P][NAD^+][HPO_4^{2-}]}

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For the reaction to be spontaneous, the Gibbs free energy of the reaction must come out to be negative.

As, the Gibbs free energy of the reaction is positive. The reaction is said to be non-spontaneous.

Hence, the given reaction is non-spontaneous in nature.

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