Write a mechanism for the bromination of acetanilide with bromine in acetic acid. Be as complete as possible and include all rel
evant resonance structures.
1 answer:
Answer:
See figure 1 and 2
Explanation:
In this case, we can start with the general reaction. Acetanilide with bromine in acetic acid we will produce <u>p-bromo-acetanilide</u> (See figure 1).
In the reaction mechanism, we have as first step the attack of the double bond in the benzene ring to one of the Br atoms in bromine () and a positive carbon will be produced in benzene. This positive charge can be moved inside of the benzne ring producing the r<u>esonance structures A, B and D</u>. Resonance structure C is produced when a double bond is generating between the "N" atom and the carbon in the benzene ring.
The final step in the mechanism is when we remove the "H" atom in structure A to produce again the double bond.
See figure 2
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Answer:
Therefore = -1835 KJ
Explanation:
Enthalpy is denoted by H.
Enthalpy: Total heat change in a chemical reaction is called enthalpy.
The change of entalpy of a reaction is denoted by
Hass's Law:The change in enthalpy of any process can be determined by calculating the sum of change in enthalpy of each of the steps involved in the process.
g= gas
S= solid
P₄(g)+10Cl₂(g)→ 4Cl₅(s) =?
PCl₅(s)→ PCl₃(g)+Cl₂(g) .......(1) = +157KJ
P₄(g)+6Cl₂(g)→ 4PCl₃(g).............(2) = -1207 KJ
If we flip a reaction the value of enthalpy will be change positive to negative or nagative to positive but the numerical value will be remain same.
We need rearrange the equation (1) because in the required equation Cl₂ is on the left side. So we flip the first equation.
PCl₃(g)+Cl₂(g)→PCl₅(s)......(3) = -157KJ
Multiplying 4 with equation (3)
4 PCl₃(g)+4Cl₂(g)→4PCl₅(s)......(4) =4×( -157)KJ= -628 KJ
Adding equation (2) and (4) we get
P₄(g)+6Cl₂(g)+4 PCl₃(g)+4Cl₂(g)→4PCl₃(g)+4PCl₅(s) =( -1207-628)KJ
⇒P₄(g)+10Cl₂(g)→4PCl₃(g)-4PCl₃(g)+4PCl₅(s) = - 1835KJ
⇒P₄(g)+10Cl₂(g)→ 4Cl₅(s) = -1835 KJ
Therefore = -1835 KJ
Answer:
11.9 is the pOH of a 0.150 M solution of potassium nitrite.
Explanation:
Solution : Given,
Concentration (c) = 0.150 M
Acid dissociation constant =
The equilibrium reaction for dissociation of (weak acid) is,
initially conc. c 0 0
At eqm.
First we have to calculate the concentration of value of dissociation constant .
Formula used :
Now put all the given values in this formula ,we get the value of dissociation constant .
By solving the terms, we get
No we have to calculate the concentration of hydronium ion or hydrogen ion.
Now we have to calculate the pH.
pH + pOH = 14
pOH =14 -2.1 = 11.9
Therefore, the pOH of the solution is 11.9