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2 years ago

Someone please quickly help

Chemistry

1 answer:

Llana [10]2 years ago

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Calculate the ph of a dilute solution that contains a molar ratio of potassium acetate to acetic acid (pka ???? 4.76) of (a) 2:1

givi [52]

According to Hasselbach-Henderson equation:

$pH=pK_{a}+log\frac{[A^{-}]}{[HA]}$

Here, $[A^{-}]$ is concentration of conjugate base and [HA] is concentration of acid.

In the given problem, conjugate base is $CH_{3}COOK$ and acid is $CH_{3}COOH$ thus, Hasselbach-Henderson equation will be as follows:

$pH=pK_{a}+log\frac{[CH_{3}COOK]}{[CH_{3}COOH]}$ ...... (1)

(a) Ratio of concentration of potassium acetate and acetic acid is 2:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=2$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{2}{1}=5.06$

Therefore, pH of solution is 5.06.

(b) Ratio of concentration of potassium acetate and acetic acid is 1:3 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{1}{3}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{3}=4.28$

Therefore, pH of solution is 4.28.

(c)Ratio of concentration of potassium acetate and acetic acid is 5:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{5}{1}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{5}{1}=5.45$

Therefore, pH of solution is 5.45.

(d) Ratio of concentration of potassium acetate and acetic acid is 1:1 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=1$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{1}=4.76$

Therefore, pH of solution is 4.76.

(e) Ratio of concentration of potassium acetate and acetic acid is 1:10 thus,

$\frac{[CH_{3}COOK]}{[CH_{3}COOH]}=\frac{1}{10}$

Also, $pK_{a}=4.76$

Putting the values in equation (1),

$pH=4.76+log\frac{1}{10}=3.76$

Therefore, pH of solution is 3.76.

4 0

2 years ago

A substance with a high [h ] would likely have which additional characteristics?

Ray Of Light [21]

Answer:

Is [h] really [H]? What characteristics are mentioned?

Explanation:

A high [H} means high acid concentration.

6 0

2 years ago