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Lana71 [14]
4 years ago
5

Add formal charges to each resonance form of hcno below.based on the formal charges you added above, which structure is favored?

Chemistry
1 answer:
Nastasia [14]4 years ago
8 0
Q1)
formal charges for atoms are assigned, this charge can be calculated using the following formula;
f.c = number of valence electrons - non bonding electrons around the atom - number of bonds

3 structures have been given, lets calculate for each structure 
A. 
charges for the atoms 
 H = 1-0-1=0
C = 4 -4-2 = -2
N = 5 - 0-4 = 1
O = 6 - 2 - 3 = 1

B.
H = 1-0-1 = 0
C = 4 - 0 - 4 =0
N = 5 - 0 - 4 = 1
O = 6 - 6 - 1 = -1

C.
H = 1-0-1 = 0
C = 4 - 2 - 3 = -1
N = 5 - 0 - 4 = 1
O = 6 - 4 - 2 = 0

Q2)
next we need to see which structure is most favoured.
the structure with least number of atoms that have a charge.
structure B and C have 2 atoms with charges whereas A has three atoms with charges, including an atom with -2 charge which is not common. so structure A can be disregarded.
another rule is that the more electronegative atom should have the more negative charge than less electronegative atoms. In structure C, Carbon the less electronegative atom compared to N and O, has -1 value and its more negative than the charges on N and O.
structure B on the other hand, O the more electronegative atom has -1 charge and C has 0 charge. Therefore the more favoured structure is B.

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The natural abundances of elements in the human body, expressed as percent by mass, are: oxygen (O),65 percent; carbon (C), 18 p
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The mass in grams of each element in the body of 62 Kg are

Oxygen               40300 g

Carbon                11160 g

Hydrogen            6200 g

Nitrogen              1860 g

Calcium                992 g

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Other elements   744 g

It is possible to check it adding all the components, the total is 62000 g.  

Explanation:

Firstly, we have a total mass of 62 Kg and the composition as a percentage of each component.

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Oxygen               65.0

Carbon               18.0

Hydrogen            10.0

Nitrogen              3.0

Calcium               1.6

Phosphorus         1.2

Other elements   1.2

Taking the definition of a percentage as part of hundred total, each percentage can be expressed as a decimal number. We should divide the percentage with 100 of total. For example: Oxygen 65%, it means 65/100 = 0.65. So, Oxygen is 0.65 in decimal numbers. We do the same for each component.

                           Percentage ( %)      Decimal number

Oxygen               65.0                         65/100 = 0.65

Carbon               18.0                           18/100 = 0.18

Hydrogen            10.0                         10/100 = 0.10

Nitrogen              3.0                           3/100 = 0.03

Calcium               1.6                           1.6/100 = 0.016

Phosphorus         1.2                           1.2/100 = 0.012

Other elements   1.2                           1.2/100 = 0.012

Finally. We can multiply decimal number of each component taking the total. 1 Kg is equivalent to 1000 g.

So, 62 Kg = 62 * 1000 g = 62000 g

After that we get the mass in grams of each element, by multiplying 62000 g and the decimal number of each component as follows:

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Oxygen               65.0                         65/100 = 0.65         0.65*62000=40300

Carbon               18.0                           18/100 = 0.18         0.18*62000=  11160

Hydrogen            10.0                         10/100 = 0.10         0.10*62000=   6200

Nitrogen              3.0                           3/100 = 0.03          0.03*62000= 1860

Calcium               1.6                           1.6/100 = 0.016        0.016*62000= 992

Phosphorus         1.2                           1.2/100 = 0.012        0.012*62000=744

Other elements   1.2                           1.2/100 = 0.012        0.012*62000=744  

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