<u>Answer:</u> The initial amount of Uranium-232 present is 11.3 grams.
<u>Explanation:</u>
All the radioactive reactions follows first order kinetics.
The equation used to calculate half life for first order kinetics:
![t_{1/2}=\frac{0.693}{k}](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D%5Cfrac%7B0.693%7D%7Bk%7D)
We are given:
![t_{1/2}=68.9yrs](https://tex.z-dn.net/?f=t_%7B1%2F2%7D%3D68.9yrs)
Putting values in above equation, we get:
![k=\frac{0.693}{68.9}=0.0101yr^{-1}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B0.693%7D%7B68.9%7D%3D0.0101yr%5E%7B-1%7D)
Rate law expression for first order kinetics is given by the equation:
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = ![0.0101yr^{-1}](https://tex.z-dn.net/?f=0.0101yr%5E%7B-1%7D)
t = time taken for decay process = 206.7 yrs
= initial amount of the reactant = ?
[A] = amount left after decay process = 1.40 g
Putting values in above equation, we get:
![0.0101yr^{-1}=\frac{2.303}{206.7yrs}\log\frac{[A_o]}{1.40}](https://tex.z-dn.net/?f=0.0101yr%5E%7B-1%7D%3D%5Cfrac%7B2.303%7D%7B206.7yrs%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B1.40%7D)
![[A_o]=11.3g](https://tex.z-dn.net/?f=%5BA_o%5D%3D11.3g)
Hence, the initial amount of Uranium-232 present is 11.3 grams.