The given question is incomplete. The complete question is as follows.
Sodium sulfate is slowly added to a solution containing 0.0500 M
and 0.0390 M
. What will be the concentration of
(aq) when
begins to precipitate? What percentage of the
can be separated from the Ag(aq) by selective precipitation?
Explanation:
The given reaction is as follows.

= 0.0390 M
When
precipitates then expression for
will be as follows.
![K_{sp} = [Ag^{+}]^{2}[SO^{2-}_{4}]](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%20%5BAg%5E%7B%2B%7D%5D%5E%7B2%7D%5BSO%5E%7B2-%7D_%7B4%7D%5D)
![1.20 \times 10^{-5} = (0.0390)^{2} \times [SO^{2-}_{4}]](https://tex.z-dn.net/?f=1.20%20%5Ctimes%2010%5E%7B-5%7D%20%3D%20%280.0390%29%5E%7B2%7D%20%5Ctimes%20%5BSO%5E%7B2-%7D_%7B4%7D%5D)
= 0.00788 M
Now, equation for dissociation of calcium sulfate is as follows.

![K_{sp} = [Ca^{2+}][SO^{2-}_{4}]](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%20%5BCa%5E%7B2%2B%7D%5D%5BSO%5E%7B2-%7D_%7B4%7D%5D)
![4.93 \times 10^{-5} = [Ca^{2+}] \times 0.00788](https://tex.z-dn.net/?f=4.93%20%5Ctimes%2010%5E%7B-5%7D%20%3D%20%5BCa%5E%7B2%2B%7D%5D%20%5Ctimes%200.00788)
= 0.00625 M
Now, we will calculate the percentage of
remaining in the solution as follows.

= 12.5%
And, the percentage of
that can be separated is as follows.
100 - 12.5
= 87.5%
Thus, we can conclude that 87.5% will be the concentration of
when
begins to precipitate.
Answer:
1.991 kJ
Explanation:
Calculate the amount of heat ( J )
CH4 ;
coefficients are : a = 19.89 , b = 5.02 * 10^-2 , c = 1.269 * 10^-5 , d = -11.01 * 10^-9
attached below is the detailed solution
Answer:
for the given reaction is -99.4 J/K
Explanation:
Balanced reaction: 
![\Delta S^{0}=[1mol\times S^{0}(NH_{3})_{g}]-[\frac{1}{2}mol\times S^{0}(N_{2})_{g}]-[\frac{3}{2}mol\times S^{0}(H_{2})_{g}]](https://tex.z-dn.net/?f=%5CDelta%20S%5E%7B0%7D%3D%5B1mol%5Ctimes%20S%5E%7B0%7D%28NH_%7B3%7D%29_%7Bg%7D%5D-%5B%5Cfrac%7B1%7D%7B2%7Dmol%5Ctimes%20S%5E%7B0%7D%28N_%7B2%7D%29_%7Bg%7D%5D-%5B%5Cfrac%7B3%7D%7B2%7Dmol%5Ctimes%20S%5E%7B0%7D%28H_%7B2%7D%29_%7Bg%7D%5D)
where
represents standard entropy.
Plug in all the standard entropy values from available literature in the above equation:
![\Delta S^{0}=[1mol\times 192.45\frac{J}{mol.K}]-[\frac{1}{2}mol\times 191.61\frac{J}{mol.K}]-[\frac{3}{2}mol\times 130.684\frac{J}{mol.K}]=-99.4J/K](https://tex.z-dn.net/?f=%5CDelta%20S%5E%7B0%7D%3D%5B1mol%5Ctimes%20192.45%5Cfrac%7BJ%7D%7Bmol.K%7D%5D-%5B%5Cfrac%7B1%7D%7B2%7Dmol%5Ctimes%20191.61%5Cfrac%7BJ%7D%7Bmol.K%7D%5D-%5B%5Cfrac%7B3%7D%7B2%7Dmol%5Ctimes%20130.684%5Cfrac%7BJ%7D%7Bmol.K%7D%5D%3D-99.4J%2FK)
So,
for the given reaction is -99.4 J/K
Sand dunes would be created due to the mixture falling on each other
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