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Advocard [28]
4 years ago
8

These equations below show two standard reduction potentials. Fe3+(aq) + e– Fe2+(aq) Eo = +0.77 Cu2+(aq) + 2e– Cu(s) Eo = +0.34

Which value represents the standard cell potential of the spontaneous overall reaction? Use E cell = E red, cathode – E red, anode. –1.11 V –0.43 V +0.43 V +1.11 V
Chemistry
1 answer:
IgorC [24]4 years ago
6 0
<h3>Answer:</h3>

= +0.43 V

<h3>Explanation:</h3>

The two standard reduction potentials are;

Fe³⁺(aq) + e⁻ → Fe²⁺(aq) E₀ = +0.77 V

Cu²⁺(aq) + 2e⁻ → Cu(s)    E₀ = +0.34 V

The overall reaction is;

Fe³⁺(aq) + Cu(s) → Fe²⁺(aq) + Cu²⁺(aq)

To calculate the standard cell potential of the overall reaction, we use the equation;

Ecell = E redu, cathode - E red, anode

From the reaction; Copper lost electrons to form copper ions (Cu²⁺) (Oxidation) while Fe³⁺ gained electrons to form Fe²⁺ (reduction)

Therefore;

E cell = + 0.77 v - (+0.34 v)

        = + 0.43 V

Hence, the standard cell potential of the overall reaction is +0.43 V

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Answer:

an element.

Explanation:

When all the atoms contain a nucleus with the same amount of protons then each atom is classified as the same element. Hence multiple atoms and a larger quantity of atoms of the same element is still just the same single element.

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Salicylic acid (C₇H₆O₃) reacts with acetic anhydride (C₄H₆O₃) to form acetylsalicylic acid (C₉H₈O₄).
lions [1.4K]

Answer:

The limiting reactant is the Salicylic acid (C₇H₆O₃)

Explanation:

In order to find the limting reactant or the excess reactant of a chemical reaction we have to compare the moles of each reactant to the stoichiometry of the reaction; we usually make rules of three.

First of all we need to convert the mass of the reactants, to moles:

70 g / 138 g/mol = 0.507 moles of salicylic acid

80g / 102 g/mol = 0.784 moles of acetic anhydride

The reaction is: 2C₇H₆O₃ (aq) + C₄H₆O₃(aq) → 2C₉H₈O₄(aq) + H₂O(l)

Ratio is 2:1.

2 moles of salicylic acid need 1 mol of acetic anhydride to react

Then, 0.507 moles of salicylic will react with (0.507 . 1) / 2 = 0.254 moles of acetic anhydride (It's ok, I have 0.784 moles and I only need 0.254 moles, so acetic anhydride still remains, the C₄H₆O₃ is the excess reactant)

In conclussion, the limiting reactant is the Salicylic acid (C₇H₆O₃)

Let's verify: 1 mol of anhyride  needs 2 moles of salicylic acid

Therefore, 0.784 moles of anhydride  will react with (0.784 . 2) /1 = 1.57 moles. → We do not have enough C₇H₆O₃, we have 0.507 moles but we need 1.57.

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3 years ago
Describe the contributions of 3 scientists to our current understanding of the atom
bogdanovich [222]

Answer:

1. Rutherford did the scattering experiment and observed that some of the rays bounce back. He concluded that there is a mass in which positive charge is concentrated. This marks the discovery of nucleus.

2. J.J Thomson discovered electrons by conducting cathode ray experiment.

3. Dalton postulated that matter is made up of small particles caled atoms

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3 years ago
I2(g) + Cl2(g)2ICl(g) Using standard thermodynamic data at 298K, calculate the entropy change for the surroundings when 1.62 mol
galina1969 [7]

Answer:

The change in entropy of the surrounding is -146.11 J/K.

Explanation:

Enthalpy of formation of iodine gas = \Delta H_f_{(I_2)}=62.438 kJ/mol

Enthalpy of formation of chlorine gas = \Delta H_f_{(Cl_2)}=0 kJ/mol

Enthalpy of formation of ICl gas = \Delta H_f_{(ICl)}=17.78 kJ/mol

The equation used to calculate enthalpy change is of a reaction is:  

\Delta H_{rxn}=\sum [n\times \Delta H_f(product)]-\sum [n\times \Delta H_f(reactant)]

For the given chemical reaction:

I_2(g)+Cl_2(g)\rightarrow 2ICl(g),\Delta H_{rxn}=?

The equation for the enthalpy change of the above reaction is:

\Delta H_{rxn}=[(2\times \Delta H_f_{(ICl)})]-[(1\times \Delta H_f_{(I_2)})+(1\times \Delta H_f_{(Cl_2)})]

=[2\times 17.78 kJ/mol]-[1\times 0 kJ/mol+1\times 62.436 kJ/mol]=-26.878 kJ/mol

Enthaply change when 1.62 moles of iodine gas recast:

\Delta H= \Delta H_{rxn}\times 1.62 mol=(-26.878 kJ/mol)\times 1.62 mol=-43.542 kJ

Entropy of the surrounding = \Delta S^o_{surr}=\frac{\Delta H}{T}

=\frac{-43.542 kJ}{298 K}=\frac{-43,542 J}{298 K}=-146.11 J/K

1 kJ = 1000 J

The change in entropy of the surrounding is -146.11 J/K.

4 0
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