Fertilizers are not pesticides. Fertilizers helps to improve plant yield by supplying nutrients needed for plant growth and food formation. When fertilizers are applied to plants, the nutrient pool increases and plants can readily grow without any deficiency resulting from lack of one mineral or the other.
1st and 4th options are suitable answers, as these 2 changes are not exactly physical changes as it cant return back to original form and as well as its not cooling, so I feel its 1st and 4th options