Answer:
(c) The retention time would be higher (d) The retention time would be lower.
Explanation:
For the polar solutes which were separated using the hydrophilic interaction chromatography (HILIC) with a strongly polar bonded phase, the retention time would be higher if eluent were changed from 80 vol% to 90 vol% acetonitrile in water.
However, for the polar solutes which were separated using the normal-phase chromatography on bare silica with methyl t=butyl ether and 2-propanol solvent, the retention time would be lower if the eluent were changed from 40 vol% to 60 vol% 2-propanol.
Metals naturally form cations.
The appropriate response is Mg2+. It has the smallest radius the would mean the littlest separation from it's the furthest shell to the core
Since magnesium has one less shell that calcium, Mg would have a little nuclear range. Besides, a particle of a component will have a little nuclear sweep than it's molecule be utilized as a part of its particle frame it has lost a shell
<u>Answer:</u> The value of
is 0.136 and is reactant favored.
<u>Explanation:</u>
Equilibrium constant in terms of concentration is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as ![K_{c}](https://tex.z-dn.net/?f=K_%7Bc%7D)
For the chemical reaction between carbon monoxide and hydrogen follows the equation:
![N_2(g)+3H_2(g)\rightleftharpoons 2NH_3(g)](https://tex.z-dn.net/?f=N_2%28g%29%2B3H_2%28g%29%5Crightleftharpoons%202NH_3%28g%29)
The expression for the
is given as:
![K_{c}=\frac{[NH_3]^2}{[N_2][H_2]^3}](https://tex.z-dn.net/?f=K_%7Bc%7D%3D%5Cfrac%7B%5BNH_3%5D%5E2%7D%7B%5BN_2%5D%5BH_2%5D%5E3%7D)
We are given:
![[NH_3]=0.25M](https://tex.z-dn.net/?f=%5BNH_3%5D%3D0.25M)
![[H_2]=0.75M](https://tex.z-dn.net/?f=%5BH_2%5D%3D0.75M)
![[N_2]=1.1M](https://tex.z-dn.net/?f=%5BN_2%5D%3D1.1M)
Putting values in above equation, we get:
![K_c=\frac{(0.25)^2}{1.1\times (0.75)^3}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%280.25%29%5E2%7D%7B1.1%5Ctimes%20%280.75%29%5E3%7D)
![K_c=0.135](https://tex.z-dn.net/?f=K_c%3D0.135)
There are 3 conditions:
- When
; the reaction is product favored. - When
; the reaction is reactant favored. - When
; the reaction is in equilibrium.
For the given reaction, the value of
is less than 1. Thus, the reaction is reactant favored.
Hence, the value of
is 0.136 and is reactant favored.
0.500 moles is roughly .5*6.022*10^23=3.011*10^23 atoms. This is independent of STP.