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Karo-lina-s [1.5K]
3 years ago
7

Why a finely powdered sample should be used in a melting point measurement?

Chemistry
1 answer:
lapo4ka [179]3 years ago
6 0

because it a essential for good heat transfer

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If the concentrated form of blood expander is 9.0 mol/L and one of your companions, a nurse, tells you that you need to have a f
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What is a change in a substance that does not involve the identity of the substance
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The vapor above a mixture of pentane and hexane at room temperature contains 35.5% pentane by mass. What is the mass percent com
FrozenT [24]
  • The mass percent of Pentane in solution is 16.49%
  • The mass percent of Hexane in solution is 83.51%

<u>Explanation</u>:

  • Take 1 kg basis for the vapor: 35.5 mass% pentane = 355 g pentane with 645 g hexane.
  • Convert these values to mol% using their molecular weights:

Pentane: Mp = 72.15 g/mol -> 355g/72.15 g/mol = 4.92mol

Hexane: Mh = 86.18 g/mol -> 645g/86.18 g/mol = 7.48mol

Pentane mol%: yp = 4.92/(4.92+7.48) = 39.68%

Hexane mol%: yh = 100 - 39.68 = 60.32%

Pp-vap = 425 torr = 0.555atm

Ph-vap = 151 torr = 0.199atm

  • From Raoult's law we know:  

Pp = xp \times Pp - vap = yp \times Pt                                       (1)

Ph = xh \times Ph - vap = yh \times Pt                                       (2)

  • Since it is a binary mixture we can write xh = (1 - xp) and yh = (1 - yp), therefore (2) becomes:

(1 - xp) \times Ph - vap = (1 - yp) \times Pt                                   (3)

  • Substituting (1) into (3) we get:

(1-xp) \times Ph - vap = (1 - yp) \times xp \times Pp - vap / yp            (4)

  • Rearrange for xp:

xp = Ph - vap / (Pp - vap/yp - Pp - vap + Ph - vap)      (5)

  • Subbing in the values we find:

Pentane mol% in solution: xp = 19.08%  

Hexane mol% in solution: xh = 80.92%

  • Now for converting these mol% to mass%, take 1 mol basis for the solution and multiplying it by molar mass:

mp = 0.1908 mol \times 72.15 g/mol

     = 13.766 g

mh = 0.8092 mol \times 86.18 g/mol

     = 69.737 g

  • Mass% of Pentane solution = 13.766/(13.766+69.737)

                                                       = 16.49%

  • Mass% of Hexane solution  = 83.51%
8 0
4 years ago
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