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CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at 25 ∘C under these conditions: PCO2PCCl4PCOCl2===0.140 atm0.185 atm0.7

padilas [110]

Answer: The $\Delta G$ for the reaction is 54.425 kJ/mol

Explanation:

For the given balanced chemical equation:

$CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)$

We are given:

$\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol$

To calculate $\Delta G^o_{rxn}$ for the reaction, we use the equation:

$\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]$

For the given equation:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]$

Putting values in above equation, we get:

$\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J$

Conversion factor used = 1 kJ = 1000 J

The expression of $K_p$ for the given reaction:

$K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}$

We are given:

$p_{COCl_2}=0.735atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.185atm$

Putting values in above equation, we get:

$K_p=\frac{(0.735)^2}{0.410\times 0.185}\\\\K_p=20.85$

To calculate the gibbs free energy of the reaction, we use the equation:

$\Delta G=\Delta G^o+RT\ln K_p$

where,

$\Delta G$ = Gibbs' free energy of the reaction = ?

$\Delta G^o$ = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = $8.314J/K mol$

T = Temperature = $25^oC=[25+273]K=298K$

$K_p$ = equilibrium constant in terms of partial pressure = 20.85

Putting values in above equation, we get:

$\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(20.85))\\\\\Delta G=54425.26J/mol=54.425kJ/mol$

Hence, the $\Delta G$ for the reaction is 54.425 kJ/mol

7 0

3 years ago

92 grams of ethanol,C2H5OH, is dissolved in 1 liter of solution. Determine the molarity (M)

const2013 [10]

Answer: 1.997 M

Explanation:

molarity = moles of solute/liters of solution or $M = \frac{mol}{L}$

first we have to find our moles of solute (mol), which you can find by dividing the mass of solute by molar mass of solute

mass of solute: 92 g

molar mass of solute: 46.08 g/mol

let's plug it in:

$\frac{92 g}{46.08 g/mol} = 1.997 mol$

next, we plug it into our original equation:

$\frac{1.997mol}{1 L} = 1.997 M$

4 0

3 years ago

All of the substances on the periodic table are classified as elements except

zzz [600]

Answer: all elements in the periodic table is classified as elements

Explanation:

The structure of the table shows periodic trends. The seven rows of the table, called periods, generally have metals on the left and nonmetals on the right. The columns, called groups, contain elements with similar chemical behaviours. Six groups have accepted names as well as assigned numbers: for example, group 17 elements are the halogens; and group 18 are the noble gases

6 0

3 years ago

Hydrogenation reactions, in which H2 and an "unsaturated" organic compound combine, are used in the food, fuel, and polymer indu

ddd [48]

Answer: The amount of heat released is 56 MJ.

Explanation:

To calculate the number of moles, we use the equation:

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$