Ans: Have the same number of electron shells
C; The Valence electrons spend more time around the atom of F
H2(g) +C2H4(g)→C2H6(g)
H-H +H2C =CH2→H3C-Ch3
2C -H bonds and one C-C bond are formed while enthalpy change (dH) of the reaction,
H-H: 432kJ/mol
C=C: 614kJ/mol
C-C: 413 kJ/mol
C-C: 347 kJ/mol
dH is equal to sum of the energies released during the formation of new bonds or negative sign, and sum of energies required to break old bonds or positive sign.
The bond which breaks energy is positive.
432+614 =1046kJ/mol
Formation of bond energy is negative
2(413) + 347 = 1173 kJ/mol
dH reaction is -1173 + 1046 =-127kJ/mol
The isotope that is more abundant, given the data is isotope Li7
<h3>Assumption</h3>
- Let Li6 be isotope A
- Let Li7 be isotope B
<h3>How to determine whiche isotope is more abundant</h3>
- Molar mass of isotope A (Li6) = 6.02 u
- Molar mass of isotope B (Li7) = 7.02 u
- Atomic mass of lithium = 6.94 u
- Abundance of A = A%
- Abundance of B = (100 - A)%
Atomic mass = [(mass of A × A%) / 100] + [(mass of B × B%) / 100]
6.94 = [(6.02 × A%) / 100] + [(7.02 × (100 - A)) / 100]
6.94 = [6.02A% / 100] + [702 - 7.02A% / 100]
6.94 = [6.02A% + 702 - 7.02A%] / 100
Cross multiply
6.02A% + 702 - 7.02A% = 6.94 × 100
6.02A% + 702 - 7.02A% = 694
Collect like terms
6.02A% - 7.02A% = 694 - 702
-A% = -8
A% = 8%
Thus,
Abundance of B = (100 - A)%
Abundance of B = (100 - 8)%
Abundance of B = 92%
SUMMARY
- Abundance of A (Li6) = 8%
- Abundance of B (Li7) = 92%
From the above, isotope Li7 is more abundant.
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