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REY [17]
3 years ago
6

An atom of nitrogen has seven electrons. Which diagram correctly represents the arrangement of these electrons?

Chemistry
1 answer:
gizmo_the_mogwai [7]3 years ago
8 0

Answer:

Option C.

Explanation:

The arrangement of electrons in their orbital follows certain rules.

The Hund's rule practically explained how electrons are distributed in their orbitals.

The Hund's rule states that electrons distributed among the orbitals of the same shell singly (without partner) before pairing occurs.

In the filling of these electrons in their orbitals, we fill in the electron without pairing first because electrons tends to repel each other before filling with the opposite spin as shown in the attached photo.

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What volumes of 0.200 M HCOOH and 2.00 M NaOH would make 500. mL of a buffer with the same pH as a buffer made from 475 mL of 0.
Hitman42 [59]

Explanation:

The given data is as follows.

      [HCOOH] = 0.2 M,       [NaOH] = 2.0 M,

         V = 500 ml,   [Benzoic acid] = 0.2 M

First, we will calculate the number of moles of benzoic acid as follows.

   No. of moles of benzoic acid = Molarity × Volume

                         = 2 \times 0.475

                         = 0.095 mol

And, moles of NaOH present in the solution will be as follows.

    No. of moles of NaOH = Molarity × Volume

                          = 2 \times 0.025

                          = 0.05 mol

Hence, the ICE table for the chemical equation will be as follows.

         C_{6}H_{5}COOH + NaOH \rightarrow C_{6}H_{5}COONa + H_{2}O

Initial:        0.095           0.05            0             0

Equlbm:  (0.095 - 0.05)  0            0.05

        pH = pK_{a} + log \frac{Base}{Acid}  

              = 4.2 + log \frac{0.05}{0.045}

              = 4.245

For,  

         HCOOH + NaOH \rightarrow HCOONa + H_{2}O

Initial:       0.2x     2(0.5 - x)               0

Equlbm:   0.2x - 2(0.5 - x)                 0             2(0.5 - x)

As,

           pH = pK_{a} + log \frac{Base}{Acid}  

          4.245 = 3.75 + log \frac{Base}{Acid}

      log \frac{Base}{Acid} = 0.5

    \frac{Base}{Acid} = 3.162

Now,

        \frac{2(0.5 - x)}{0.2x - 2(0.5 - x)} = 3.162

               x = 0.464 L

Volume of NaOH = (0.5 - 0.464) L

                             = 0.036 L

                             = 36 ml               (as 1 L = 1000 mL)

And, volume of formic acid is 464 mL.

                 

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