determine the rate of a reaction that follows the rate law: rate=k[A]m[B]n, where: k= 1x10-2 [A]=2 M B= 3 M m=2 n=1?

The first-order rate constant for the reaction of methyl chloride (CH3Cl) with water to produce methanol (CH3OH) and hydrochlori

Dvinal [7]

Answer:

K(48.5°C) = 1.017 E-8 s-1

Explanation:

CH3Cl + H2O → CH3OH + HCl

at T1 = 25°C (298 K) ⇒ K1 = 3.32 E-10 s-1

at T2 = 48.5°C (321.5 K) ⇒ K2 = ?

Arrhenius eq:

K(T) = A e∧(-Ea/RT)
Ln K = Ln(A) - [(Ea/R)(1/T)]

∴ A: frecuency factor

∴ R = 8.314 E-3 KJ/K.mol

⇒ Ln K1 = Ln(A) - [Ea/R)*(1/T1)]..........(1)

⇒ Ln K2 = Ln(A) - [(Ea/R)*(1/T2)].............(2)

(1)/(2):

⇒ Ln (K1/K2) = (Ea/R)* (1/T2-1/T1)

⇒ Ln (K1/K2) = (116 KJ/mol/8.3134 E-3 KJ/K.mol)*(1/321.5 K - 1/298 K)

⇒ Ln (K1/K2) = (13952.37 K)*(- 2.453 E-4 K-1)

⇒ Ln (K1/K2) = - 3.422

⇒ K1/K2 = e∧(-3.422)

⇒ (3.32 E-10 s-1)/K2 = 0.0326

⇒ K2 = (3.32 E-10 s-1)/0.0326

⇒ K2 = 1.017 E-8 s-1

7 0

3 years ago

Which fraction contains the largest molecules? A) diesel B)gasoline C)kerosene?

OLga [1]

The answer is A because of the shear thickness of diesel fuel

3 0

2 years ago

The element with 8 electrons in its 3d sublevel is a. O. b. Ne. c. Ar. d. Ni.

Evgesh-ka [11]

The element with 8 electrons in its 3d sublevel is Ni, Nickel. The answer is letter D. The rest of the choices do not answer the question above.

5 0

3 years ago

Read 2 more answers

Question 3 When the population size decreases over time, the total number of births the total number of deaths. O less than O eq

Neporo4naja [7]

The population decreases when the birth rate is less than the death rate.

4 0

2 years ago

Calculate the maximum volume (in mL) of 0.143 M HCl that each of the following antacid formulations would be expected to neutral

Nuetrik [128]

Answer:

a. The maximum volume of 0.143 M HCl required is 154.4 mL.

b. The maximum volume of 0.143 M HCl required is 135.7 mL.

Explanation:

a.

$Al(OH)_3+3HCl\rightarrow AlCl_3+3H_2O$

Mass of aluminum hydroxide = 350 mg = 0.350 g ( 1mg = 0.001 g)

Moles of aluminum hydroxide = $\frac{0.350 g}{78 g/mol}=0.004487 mol$

According to reaction ,3 moles of HCl neutralize 1 mole of aluminum hydroxide.Then 0.004487 mole of aluminum hydroxide will be neutralize by :

$\frac{3}{1}\times 0.004487 mol=0.01346 mol$ of HCl.

$Mg(OH)_2+2HCl\rightarrow MgCL_2+2H_2O$

Mass of magnesium hydroxide = 250 mg = 0.250 g ( 1mg = 0.001 g)

Moles of magnesium hydroxide = $\frac{0.250 g}{58 g/mol}=0.004310 mol$

According to reaction ,2 moles of HCl neutralize 1 mole of magnesium hydroxide.Then 0.004310 mole of magnesium hydroxide will be neutralize by :

$\frac{2}{1}\times 0.004310 mol=0.008621 mol$ of HCl.

Total moles of HCl required to neutralize both :

0.01346 mol + 0.008621 mol = 0.02208 mol

Molarity of the HCL solution = 0.143 M

Volume of the solution = V

$Molarity=\frac{\text{Total moles of HCl}{\text{Volume in Liter}}$

$V=\frac{0.02208 mol}{0.143 M}=0.1544 L$

1 L = 1000 mL

0.1544 L = 154.4 mL

The maximum volume of 0.143 M HCl required is 154.4 mL.

b.

$CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2$

Mass of calcium carbonate = 970mg = 0.970 g ( 1mg = 0.001 g)

Moles of calcium carbonate = $\frac{0.970 g}{100 g/mol}=0.00970 mol$

According to reaction ,2 moles of HCl neutralize 1 mole of calcium carbonate.Then 0.00970 mole of calcium carbonate will be neutralize by :

$\frac{2}{1}\times 0.00970 mol=0.0194 mol$ of HCl.

Total moles of HCl required to neutralize calcium carbonate : 0.0194 mol

Molarity of the HCL solution = 0.143 M

Volume of the solution = V

$Molarity=\frac{\text{Total moles of HCl}}{\text{Volume in Liter}}$

$V=\frac{0.0194 mol}{0.143 M}=0.1357 L$

1 L = 1000 mL

0.1357 L = 135.7 mL

The maximum volume of 0.143 M HCl required is 135.7 mL.

4 0

3 years ago