Answer:
17.65 grams of O2 are needed for a complete reaction.
Explanation:
You know the reaction:
4 NH₃ + 5 O₂ --------> 4 NO + 6 H₂O
First you must know the mass that reacts by stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction). For that you must first know the reacting mass of each compound. You know the values of the atomic mass of each element that form the compounds:
- N: 14 g/mol
- H: 1 g/mol
- O: 16 g/mol
So, the molar mass of the compounds in the reaction is:
- NH₃: 14 g/mol + 3*1 g/mol= 17 g/mol
- O₂: 2*16 g/mol= 32 g/mol
- NO: 14 g/mol + 16 g/mol= 30 g/mol
- H₂O: 2*1 g/mol + 16 g/mol= 18 g/mol
By stoichiometry, they react and occur in moles:
- NH₃: 4 moles
- O₂: 5 moles
- NO: 4 moles
- H₂O: 6 moles
Then in mass, by stoichiomatry they react and occur:
- NH₃: 4 moles*17 g/mol= 68 g
- O₂: 5 moles*32 g/mol= 160 g
- NO: 4 moles*30 g/mol= 120 g
- H₂O: 6 moles*18 g/mol= 108 g
Now to calculate the necessary mass of O₂ for a complete reaction, the rule of three is applied as follows: if by stoichiometry 68 g of NH₃ react with 160 g of O₂, 7.5 g of NH₃ with how many grams of O₂ will it react?
mass of O₂≅17.65 g
<u><em>17.65 grams of O2 are needed for a complete reaction.</em></u>
Explanation:
(a) The given reaction equation is as follows.
(acidic)
So, here the reduction and oxidation-half reactions will be as follows.
Oxidation-half reaction:
Reduction-half-reaction:
As total charge present on reactant side is -1 and total charge present on product side is +3. And, since it is present in aqueous medium. Hence, we will balance the charge for this reaction equation as follows.
(acidic)
(b) The given reaction equation is as follows.
(basic)
So, here the reduction and oxidation-half reactions will be as follows.
Reduction-half reaction:
Oxidation-half reaction:
Hence, to balance the number of electrons in this equation we multiply it by 4 as follows.
Therefore, balancing the whole reaction equation in the basic medium as follows.
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Because, particles are moving faster in the hotter material. This speeds up the dissolving process.