Answer:
D. The temperature of the the solution increases
Explanation:
Endothermic. Endo means in and thermic means a temperature, so Endothermic means the taking in of an temperature and the only answer choices that deal with temperature is,A and D. If it absorbs temperature it's going to rise.
Answer:
A and C are true , B and D are false
Explanation:
For A)
from the first law of thermodynamics (in differential form)
dU= δQ - δW = δQ - PdV
from the second law
dS ≥ δQ/T
then
dU ≤ T*dS - p*dV
dU - T*dS + p*dV ≤ 0
from the definition of Gibbs free energy
G=H - TS = U+ PV - TS → dG= dU + p*dV + V*dp - T*dS - S*dT
dG - V*dp + S*dT = dU - T*dS + p*dV ≤ 0
dG ≤ V*dp - S*dT
in equilibrium, pressure and temperature remains constant ( dp=0 and dT=0). Thus
dG ≤ 0
ΔG ≤ 0
therefore the gibbs free energy should decrease in an spontaneous process → A reaction with a negative Gibbs standard free energy is thermodynamically spontaneous under standard conditions
For B) Since the standard reduction potential is related with the Gibbs standard free energy through:
ΔG⁰=-n*F*E⁰
then, when ΔG⁰ is negative , E⁰ is positive and therefore a coupled redox reaction with a positive standard reduction potential is thermodynamically spontaneous.
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Answer:
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Explanation:
Answer:
The mechanisms for the elimination reactions between NaOH in ethanol and the halogenoalkanes are demonstrated in the figure attached.
Explanation:
(i) 1-bromobutane will suffer elimination to for an alkene. The mechanism will be E2, which means that the attack and the elimination will occur simultaneously. This is the preferred mechanism because the bromine is in a primary carbon.
(ii) 2-bromo-2-methylpentane will suffer elimination to for an alkene. The mechanism will be E1, which means that the attack and the elimination will occur in two different steps. The bromine will be eliminated in the first step with the formation of a carbocation and in a second step the double bond will be formed after the anionic attack. This is the preferred mechanism because the bromine is in a terciary carbon which is able to stabilize the carbocation formed.