In a chemical reaction, the equilibrium constant refers to the value of its reaction quotient at chemical equilibrium, that is, a condition attained by a dynamic chemical system after adequate time has passed, and at which its composition has no measurable capacity to undergo any kind of further modification.
The given reaction is: HCN (aq) + OH⁻ = CN⁻ (aq) + H2O (l)
The equilibrium constant = product of concentration of products / product of concentration of reactants
(Here, H2O is not considered as its concentration is very high)
So, Keq = [CN⁻] / [HCN] [OH⁻]
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
A solution is prepared by dissolving biphenyl into naphthalene. We can calculate the freezing point depression (ΔT) for naphthalene using the following expression.

where,
- i: van 't Hoff factor (1 for non-electrolytes)
- Kf: cryoscopic constant
- m: molality
The normal freezing point of naphthalene is 80.26 °C. The freezing point of the solution is:

The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
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In the question, the number of atoms per unit cell is required for:
A) Polonium (Po)
In polonium, the structure is simple cubic, meaning there are 8 corner atoms, which add up to one atom per unit cell.
B) Manganese (Mn)
The structure of the Mn can be considered to be a body centered cubic (BCC) and the number of atoms for this is 8 corner atoms and 1 central atoms, making a total of 2 atoms per unit cell.
C) Silver (Ag)
Silver has a face centered cubic (FCC) unit cell structure, where there are 8 corner atoms and 6 atoms on the faces, so there are a total of 4 atoms per unit cell.