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Anastaziya [24]
3 years ago
9

Why cant flame color determine the identity of an ion

Chemistry
1 answer:
AysviL [449]3 years ago
6 0
The flame test is used to visually determine the identity of an unknown metal or metalloid ion based on the characteristic color the salt turns the flame of the bunsen burner 
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When matter changes from a solid to a liquid, the process is called __________
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Answer: melting

Explanation:

The process in which a solid changes to a liquid is called melting. The melting point is the temperature at which a solid changes to a liquid. For a given type of matter, the melting point is the same as the freezing point.

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[Co(H2O)6]2+(aq) + 4Cl-(aq) ⇌ [CoCl4]2-(aq) + 6H2O(l)
pav-90 [236]

<u>Answer:</u>

<u>For A:</u> The expression for K_{eq} is given below.

<u>For B:</u> The value of K_{eq} at 25°C is 0.0185512

<u>For C:</u> The value of K_{eq} at 65°C is 0.2887886

<u>For D:</u> The reaction is endothermic in nature.

<u>Explanation:</u>

  • <u>For A:</u>

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as K_{eq}

For the given chemical reaction:

[Co(H_2O)_6]^{2+}(aq.)+4Cl^-(aq.)\rightleftharpoons [CoCl_4]^{2-}(aq.)+6H_2O(l)

The expression of K_{eq} for above equation without the concentration of liquid water is:

K_{eq}=\frac{[CoCl_4]^{2-}}{[Co(H_2O)_6]^{2+}[Cl^-]^4}      ......(1)

The expression is written above.

  • <u>For B:</u>

We are given:

[CoCl_4]^{2-}=0.0334612M

[Co(H_2O)_6]^{2+}=0.966539M

[Cl^-]=1.86616M

Putting values in equation 1, we get:

K_{eq}=\frac{0.0334612}{0.966539\times 1.86616}=0.0185512

Hence, the value of K_{eq} at 25°C is 0.0185512

  • <u>For C:</u>

We are given:

[CoCl_4]^{2-}=0.234625M

[Co(H_2O)_6]^{2+}=0.765375M

[Cl^-]=1.06150M

Putting values in equation 1, we get:

K_{eq}=\frac{0.234625}{0.765375\times 1.06150}=0.2887886

Hence, the value of K_{eq} at 65°C is 0.2887886

  • <u>For D:</u>

For Endothermic reactions, \Delta H>0, which is positive

For Exothermic reactions, \Delta H, which is negative

To calculate \Delta H of the reaction, we use Van't Hoff's equation, which is:

\ln(\frac{K_{65^oC}}{K_{25^oC}})=\frac{\Delta H}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_{65^oC} = equilibrium constant at 65°C = 0.2887886

K_{25^oC} = equilibrium constant at 25°C = 0.0185512

\Delta H = Enthalpy change of the reaction = ?

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 25^oC=[25+2730]K=298K

T_2 = final temperature = 65^oC=[65+2730]K=338K

Putting values in above equation, we get:

\ln(\frac{0.2887886}{0.0185512})=\frac{\Delta H}{8.314J/mol.K}[\frac{1}{298}-\frac{1}{338}]\\\\\Delta H=57471.26J/mol

As, the calculated value of \Delta H>0. Thus, the reaction is endothermic in nature.

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