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2 years ago

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You make dilutions of curcumin stock solution and measure the absorbance of each dilution to obtain the following data: Conc. (M

) Abs. 1.60E-05 1.93 1.21E-05 1.62 8.09E-06 1.08 4.04E-06 0.44 2.02E-06 0.13 Which data points should you keep when making your calibration curve? Choose all that apply. (Hint: Plot the data.)

1 answer:

algol132 years ago

8 0

Answer:

The following data point should be kept when making your calibration.

1.21E-05 M

1.60E-05 M

8.09E-06 M

4.04 E-06 M

Explanation:

From the graph it is obvious that the reading for the concentration 2.02E-06 M does not fall on the straight line. So this point should not be taken to construct the calibration plot.

Find attached of the graph.

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Explanation:

Part A:

Total pressure of the mixture = P = 5.40 atm

Volume of the container = V = 10.0 L

Temperature of the mixture = T = 23°C = 296.15 K

Total number of moles of gases = n

PV = nRT (ideal gas equation)

$n=\frac{PV}{RT}=\frac{5.40 atm\times 10.0 L}{0.0821 atm L/mol K\times 296.15 K}=2.22 mol$

Moles of methane gas = $n_1=\frac{8.00 g}{16 g/mol}=0.5 mol$

Moles of ethane gas = $n_2=\frac{18.0 g}{30 g/mol}=0.6 mol$

Moles of propane gas = $n_3$

$n=n_1+n_2+n_3$

$2.22=0.5 mol +0.6 mol+ n_3$

$n_3= 2.22 mol - 0.5 mol -0.6 mol= 1.12 mol$

Mole fraction of methane = $\chi_1=\frac{n_1}{n_1+n_2+n_3}=\frac{n_1}{n}$

$\chi_1=\frac{0.5 mol}{2.22 mol}=0.2252$

Similarly, mole fraction of ethane and propane :

$\chi_2=\frac{n_2}{n}=\frac{0.6 mol}{2.22 mol}=0.2703$

$\chi_3=\frac{n_3}{n}=\frac{1.12 mol}{2.22 mol}=0.5045$

Partial pressure of each gas can be calculated by the help of Dalton's' law:

$p_i=P\times \chi_1$

Partial pressure of methane gas:

$p_1=P\times \chi_1=5.40 atm\times 0.2252=1.22 atm$

Partial pressure of ethane gas:

$p_2=P\times \chi_2=5.40 atm\times 0.2703=1.46 atm$

Partial pressure of propane gas:

$p_3=P\times \chi_3=5.40 atm\times 0.5045=2.72 atm$

Part B:

Suppose in 100 grams mixture of nitrogen and oxygen gas.

Percentage of nitrogen = 37.8 %

Mass of nitrogen in 100 g mixture = 37.8 g

Mass of oxygen gas = 100 g - 37.8 g = 62.2 g

Moles of nitrogen gas = $n_1=\frac{37.8 g g}{28g/mol}=1.35 mol$

Moles of oxygen gas = $n_2=\frac{62.2 g}{32 g/mol}=1.94 mol$

Mole fraction of nitrogen= $\chi_1=\frac{n_1}{n_1+n_2}$

$\chi_1=\frac{1.35 mol}{1.35 mol+1.94 mol}=0.4103$

Similarly, mole fraction of oxygen

$\chi_2=\frac{n_2}{n_1+n_2}=\frac{1.94 mol}{1.35 mol+1.94 mol}=0.5897$

Partial pressure of each gas can be calculated by the help of Dalton's' law:

$p_i=P\times \chi_1$

The total pressure is 405 mmHg.

P = 405 mmHg

Partial pressure of nitrogen gas:

$p_1=P\times \chi_1=405 mmHg\times 0.4103 =166.17 mmHg$

Partial pressure of oxygen gas:

$p_2=P\times \chi_2=405 mmHg\times 0.5897=238.83 mmHg$

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