Answer:
The answer is in the explanation.
Explanation:
The KHP is an acid used as standard in titrations to find concentration of bases as NaOH.
The reaction that explain this use is:
KHP + NaOH → KNaP + H2O
<em>where 1 mole of KHP reacts per mole of NaOH</em>
That means, at equivalence point of a titration in which titrant is NaOH, the moles of KHP = Moles of NaOH added
With the moles of KHP = Moles of NaOH and the volume used by titrant we can find the molar concentration of NaOH.
The moles of KHP are obtained from the volume and the concentration as follows:
Volume(L)*Concentration (Molarity,M) = moles of KHP
If the concentration is more or less than 0.100M, the moles will be higher or lower. For that reason, we need to know the concentration of KHP but is not necessary to be 0.100M.
Explanation:
Since HF is a weak acid, the use of an ICE table is required to find the pH. The question gives us the concentration of the HF.
HF+H2O⇌H3O++F−HF+H2O⇌H3O++F−
Initial0.3 M-0 M0 MChange- X-+ X+XEquilibrium0.3 - X-X MX M
Writing the information from the ICE Table in Equation form yields
6.6×10−4=x20.3−x6.6×10−4=x20.3−x
Manipulating the equation to get everything on one side yields
0=x2+6.6×10−4x−1.98×10−40=x2+6.6×10−4x−1.98×10−4
Now this information is plugged into the quadratic formula to give
x=−6.6×10−4±(6.6×10−4)2−4(1)(−1.98×10−4)−−−−−−−−−−−−−−−−−−−−−−−−−−−−√2x=−6.6×10−4±(6.6×10−4)2−4(1)(−1.98×10−4)2
The quadratic formula yields that x=0.013745 and x=-0.014405
However we can rule out x=-0.014405 because there cannot be negative concentrations. Therefore to get the pH we plug the concentration of H3O+ into the equation pH=-log(0.013745) and get pH=1.86
Answer: It would be Sp2, because H3O+ has planar structure.
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